Citation: Xing Guo CHEN, Chu Luo YANG, Jin Gui QIN, Kyuya YAKUSHI, Yasuhiro NAKAZAWA, Kenji ICHIMURA. A New Inorganic-organic Nanocomposite, 4,4'-Bipyridine Intercalated into Lamellar FePS₃[J]. Chinese Chemical Letters, ;2003, 14(11): 1179-1181. shu

A New Inorganic-organic Nanocomposite, 4,4'-Bipyridine Intercalated into Lamellar FePS₃

1.
Department of Chemistry, Wuhan University, Wuhan 430072;
2.
Institute for Molecular Science, Okazaki 444, Japan;
3.
Department of Chemistry, Faculty of Science, Kumamoto University, Kumamoto 860, Japan

Received Date: 11 November 2002

A new intercalation compound, Fe_0.85PS₃(4,4'-bipyH)_0.30 (4,4'-bipy=4,4'-bipyridine), is obtained by the intercalation of 4,4'-bipyridine·2HCl with lamellar FePS₃, which is characterized by elemental analysis, powder X-ray diffraction, infrared spectroscopy. By comparison with the pure FePS₃, the lattice spacing of Fe_0.85PS₃(4,4'-bipyH)_0.30 is expanded by~5.7(Å), indicating that the ring plane of the guest is perpendicular to the layer of the host. The magnetic property of Fe_0.85PS₃(4,4'-bipyH)_0.30 is studied with SQUID. It exhibits an antiferromagnetic phase transition with T_N of about 70 K.
- Intercalation,
- lamellar FePS₃,
- magnetic property
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