Citation: LI Yongjun, FU Yingwen, FANG Shibi, JIANG Yingyan. IONIC CONDUCTIVITY OF METHYLSILOXANE TERMINATED POLYETHYLENE OXIDE WITH LITHIUM PERCHLORATE NETWORK FILMS[J]. Chinese Journal of Polymer Science, ;1988, 6(4): 332-336. shu

IONIC CONDUCTIVITY OF METHYLSILOXANE TERMINATED POLYETHYLENE OXIDE WITH LITHIUM PERCHLORATE NETWORK FILMS

Received Date: 23 April 1987

Complex films of crosslinked poly(methylsiloxane-co-ethylene oxide) and lithium perchlorate were prepared. These solid state polymeric electrolytes show a markedly higher ionic conductivity, and excellent flexibility. The ionic conductivity of the network films closed to 10-5 Scm-1 at room temperature. The effects of Li+ content, species and contents of crosslinking agents, molecular weight of poly(ethylene oxide) and temperature on the ionic conductivity of the network films were also investigated.
1. [1]
  Qingkun Zhu , Yaodong Jin , Bao Zhang , Wei Liu , Haozhe Qin , Lei Ming , Xing Ou . Engineering a triplex ionic transport architecture for high ionic conductivity in solid-state lithium metal batteries. Chinese Chemical Letters, 2026, 37(8): 111411-. doi: 10.1016/j.cclet.2025.111411
2. [2]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
3. [3]
  Xiaofei Wang , Shuonan Wang , Zhangkuo Han , Jiahan Zheng , Yu Chen , Libing Liao , Hao Liu . Shear-engineered flower-like spherulites enable record ionic conductivity of PEO-based electrolytes for solid-state lithium batteries. Chinese Chemical Letters, 2026, 37(2): 111434-. doi: 10.1016/j.cclet.2025.111434
4. [4]
  Xiang Li , Haikun Guo , Shengchao Chai , Haibin Li , Shihao Song , Peng Zuo , Haolong Li . Polyoxometalate-based supramolecular ionic network electrolytes for flexible proton conductors. Chinese Chemical Letters, 2026, 37(4): 110750-. doi: 10.1016/j.cclet.2024.110750
5. [5]
  Qiangwei Wang , Huijiao Liu , Mengjie Wang , Haojie Zhang , Jianda Xie , Xuanwei Hu , Shiming Zhou , Weitai Wu . Observation of high ionic conductivity of polyelectrolyte microgels in salt-free solutions. Chinese Chemical Letters, 2024, 35(4): 108743-. doi: 10.1016/j.cclet.2023.108743
6. [6]
  Guangtao Zan , Shengyou Li , Kaiying Zhao . Ionic Diode Films with Asymmetric Polyelectrolyte Interfaces for Moisture-Electromagnetic Coupled Energy Harvesting. Chinese Journal of Structural Chemistry, 2025, 44(8): 100648-100648. doi: 10.1016/j.cjsc.2025.100648
7. [7]
  Jingyu Shi , Xiaofeng Wu , Yutong Chen , Yi Zhang , Xiangyan Hou , Ruike Lv , Junwei Liu , Mengpei Jiang , Keke Huang , Shouhua Feng . Structure factors dictate the ionic conductivity and chemical stability for cubic garnet-based solid-state electrolyte. Chinese Chemical Letters, 2025, 36(5): 109938-. doi: 10.1016/j.cclet.2024.109938
8. [8]
  Liang Ming , Miao Deng , Siwu Li , Ziling Jiang , Lin Li , Ziyu Lu , Qiyue Luo , Jie Yang , Zhonghui Cui , Chuang Yu . Reviving the ionic conductivity of air-instable solid-state electrolytes via a facile heat treatment. Chinese Chemical Letters, 2026, 37(7): 111114-. doi: 10.1016/j.cclet.2025.111114
9. [9]
  Mu-Xuan Wu , Li-Ling Su , Shu-Yu Sun , Chen-Xi Bi , Zhao Zheng , Wen-Jun Feng , Bo-Quan Li , Xue-Qiang Zhang , Jia-Qi Huang . Improving the uniformity of lithium deposition via ionic liquid additives for long-cycling lithium–sulfur batteries. Chinese Chemical Letters, 2026, 37(7): 111330-. doi: 10.1016/j.cclet.2025.111330
10. [10]
  Yu Wang , Kun Ding , Xuerong Gong , Shou Chen , Ao Sun , Junxi Zhang , Baofeng Wang . Hydrogen bonding-reinforced multi-component cross-linked hydrogel electrolytes with high ionic conductivity and stretchability for stabilized zinc anodes. Chinese Chemical Letters, 2026, 37(6): 111078-. doi: 10.1016/j.cclet.2025.111078
11. [11]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
12. [12]
  Chang-An Xu , Yue Yu , Yuanming Tan , Shuxi Gao , Hao Pang . Reduced graphene oxide/Fe₃O₄ composite material integrated with electromagnetic wave absorption, thermal conductivity and corrosion resistance. Chinese Chemical Letters, 2026, 37(7): 112118-. doi: 10.1016/j.cclet.2025.112118
13. [13]
  Ying Li , Yanjun Xu , Xingqi Han , Di Han , Xuesong Wu , Xinlong Wang , Zhongmin Su . A new metal–organic rotaxane framework for enhanced ion conductivity of solid-state electrolyte in lithium-metal batteries. Chinese Chemical Letters, 2024, 35(9): 109189-. doi: 10.1016/j.cclet.2023.109189
14. [14]
  Yepei Li , Kun Lin . Face-sharing strategy helps achieve lithium superionic conductivity in face-centred cubic oxides. Chinese Journal of Structural Chemistry, 2025, 44(4): 100449-100449. doi: 10.1016/j.cjsc.2024.100449
15. [15]
  Hui Gu , Mingyue Gao , Kuan Shen , Tianli Zhang , Junhao Zhang , Xiangjun Zheng , Xingmei Guo , Yuanjun Liu , Fu Cao , Hongxing Gu , Qinghong Kong , Shenglin Xiong . F127 assisted fabrication of Ge/rGO/CNTs nanocomposites with three-dimensional network structure for efficient lithium storage. Chinese Chemical Letters, 2024, 35(9): 109273-. doi: 10.1016/j.cclet.2023.109273
16. [16]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
17. [17]
  Ya Song , Mingxia Zhou , Zhu Chen , Huali Nie , Jiao-Jing Shao , Guangmin Zhou . Integrated interconnected porous and lamellar structures realized fast ion/electron conductivity in high-performance lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(6): 109200-. doi: 10.1016/j.cclet.2023.109200
18. [18]
  Liang Ming , Dan Liu , Qiyue Luo , Chaochao Wei , Chen Liu , Ziling Jiang , Zhongkai Wu , Lin Li , Long Zhang , Shijie Cheng , Chuang Yu . Si-doped Li₆PS₅I with enhanced conductivity enables superior performance for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109387-. doi: 10.1016/j.cclet.2023.109387
19. [19]
  Bing Jiang , Gang Zou , Bi Luo , Yan Guo , Jingru Li , Wendi Zhang , Qianxiao Fan , Lehao Liu , Lihua Chu , Qiaobao Zhang , Meicheng Li . Enhanced electrochemical performance of lithium-rich layered oxide materials: Exploring advanced coating strategies. Chinese Chemical Letters, 2025, 36(4): 109801-. doi: 10.1016/j.cclet.2024.109801
20. [20]
  Chi Zhang , Zhilong Wang , Xinyue Wang , Yufei Zhang , Zhiguo Zhang , An Chen , Jinjin Li , Xitian Zhang , Lili Wu . Chip−like high−entropy oxide catalysts enhance fast sulfur evolution reaction for long−life lithium−sulfur batteries. Chinese Chemical Letters, 2025, 36(12): 110551-. doi: 10.1016/j.cclet.2024.110551

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1733)
HTML views(45)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return