Citation: Li Qiang, Liu Jiajia, Li Fangni, Bing Liancheng, Ji Shengfu, Wang Guangjian. Progress in Preparation of Nano-Scale SAPO-34 Molecular Sieves and Their Application in Methanol to Olefins[J]. Chemistry, ;2019, 82(7): 585-589. shu

Progress in Preparation of Nano-Scale SAPO-34 Molecular Sieves and Their Application in Methanol to Olefins

1.
Chemical Engineering Institute, Qingdao University of Science and Technology, Qingdao 266042
2.
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029

Corresponding author: Wang Guangjian, wgjnet@126.com
Received Date: 29 January 2019
Accepted Date: 4 April 2019

SAPO-34 molecular sieve is widely used in the reaction of methanol to olefin (MTO). Traditional SAPO-34 molecular sieve is prone to carbon deposition and coking in the catalytic process, which lead to molecular sieve deactivation and short service life. Nano-scale SAPO-34 molecular sieves have smaller crystal size, higher specific surface area, less diffusion limitation, stronger catalyst activity center and anti-carbon deposition ability. In this paper, the preparation methods of nano-scale SAPO-34 were introduced from the perspectives of seed assist, additive addition, double template agent and optimization of crystallization conditions, and the effects of different conditions on the size of nano crystals were further studied and analyzed. Meanwhile, the catalytic performance of different nano-sized SAPO-34 in MTO was discussed. The current research problems and future development directions are put forward.
- Molecular sieve,
- SAPO-34,
- Hierarchical pore structure,
- Methanol to olefin,
- Nanocrystallites
1. [1]
  B M Lok, C A Messina, R L Patton et al. J. Am. Chem. Soc., 1984, 106(20): 6092~6093.
2. [2]
  D Chen, K Moljord, A Holmen. Micropor. Mesopor. Mater., 2012, 164(164): 239~250.
3. [3]
  Y Kawabuchi, H Oka, S Kawano et al. Carbon, 1998, 36(4): 377~382.
4. [4]
5. [5]
6. [6]
7. [7]
  None. Appl. Catal., 1984, 10(1): 80.
8. [8]
  T M Nenoff, S G Thoma, M Kartin. USP: 7041616, 2006.
9. [9]
  N Najafi, S Askari, R Halladj et al. Powder Technol., 2014, 254(2): 324~330.
10. [10]
11. [11]
  G Y Liu, P Tian, J Z Li et al. Micropor. Mesopor. Mater., 2008, 111(1~3): 143~149.
12. [12]
  T Z Wang, X C Lu, Y Yan. Micropor. Mesopor. Mater., 2013, 168: 155~163.
13. [13]
14. [14]
  Q M Sun, N Wang, G Q Guo et al. Chem. Commun., 2015, 51(91): 16397~16400.
15. [15]
  Q M Sun, N Wang, R S Bai et al. J. Mater. Chem. A, 2016, 4(39): 14978~14982.
16. [16]
  G R Chen, Q M Sun, J H Yu. Chem. Commun., 2017, 53(100): 13328~13331.
17. [17]
  P F Wang, D X Yang, J Hu et al. Catal. Today, 2013, 212: 62.e1~62.e8.
18. [18]
  C Wang, M Yang, P Tian et al. J. Mater. Chem. A, 2015, 3(10): 5608~5616.
19. [19]
  B Yang, P B Zhao, J H Ma et al. Chem. Phys. Lett., 2016, 665: 59~63.
20. [20]
  J W Zheng, J J Ding, D L Jin et al. Chem. Commun., 2017, 53(45): 6132~6135.
21. [21]
  P F Wu, M Yang, W N Zhang et al. Chem. Commun., 2017, 53(36): 4985~4988.
22. [22]
  P F Wu, M Yang, L J Sun et al. Chem. Commun., 2018, 54(79): 11160~11163.
23. [23]
  C Wang, M Yang, W N Zhang et al. RSC Adv., 2016, 6(53): 47864~47872.
24. [24]
  H Yang, X H Liu, G Z Lu et al. Micropor. Mesopor. Mater., 2016, 225: 144~153.
25. [25]
  S T Yang, J Y Kim, H J Chae et al. Mater. Res. Bull., 2012, 47(11): 3888~3892.
26. [26]
  N Najafi, S Askari, R Halladj. Powder Technol., 2014, 254: 324~330.
27. [27]
  H S Pajaie, M Taghizadeh. J. Ind. Eng. Chem., 2015, 24: 59~70.
28. [28]
  H S Pajaie, M Taghizadeh. Synth. React. Inorg. Mater., 2016, 46(5): 701~712.
29. [29]
  M Li, Y H Wang, L Bai et al. Appl. Catal. A, 2017, 531: 203~211.
30. [30]
  D Chen, K Moljord, T Fuglerud et al. Micropor. Mesopor. Mater., 1999, 29(1-2): 191~203.
1. [1]
  Qinhui Guan , Yuhao Guo , Na Li , Jing Li , Tingjiang Yan . Molecular sieve-mediated indium oxide catalysts for enhancing photocatalytic CO₂ hydrogenation. Acta Physico-Chimica Sinica, 2025, 41(11): 100133-0. doi: 10.1016/j.actphy.2025.100133
2. [2]
  Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-0. doi: 10.3866/PKU.WHXB202406012
3. [3]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
4. [4]
  Yi RU , Tao MENG , Zhaoteng XUE , Dongsen MAO . Synergistic catalysis of Al distribution and pore structure in ZSM-5 zeolite for bioethanol-to-propylene. Chinese Journal of Inorganic Chemistry, 2026, 42(2): 247-262. doi: 10.11862/CJIC.20250255
5. [5]
  Yufang GAO , Nan HOU , Yaning LIANG , Ning LI , Yanting ZHANG , Zelong LI , Xiaofeng LI . Nano-thin layer MCM-22 zeolite: Synthesis and catalytic properties of trimethylbenzene isomerization reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1079-1087. doi: 10.11862/CJIC.20240036
6. [6]
  Jiali CHEN , Guoxiang ZHAO , Yayu YAN , Wanting XIA , Qiaohong LI , Jian ZHANG . Machine learning exploring the adsorption of electronic gases on zeolite molecular sieves. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 155-164. doi: 10.11862/CJIC.20240408
7. [7]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
8. [8]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
9. [9]
  Xue Liu , Lipeng Wang , Luling Li , Kai Wang , Wenju Liu , Biao Hu , Daofan Cao , Fenghao Jiang , Junguo Li , Ke Liu . Research on Cu-Based and Pt-Based Catalysts for Hydrogen Production through Methanol Steam Reforming. Acta Physico-Chimica Sinica, 2025, 41(5): 100049-0. doi: 10.1016/j.actphy.2025.100049
10. [10]
  Feifei Yang , Wei Zhou , Chaoran Yang , Tianyu Zhang , Yanqiang Huang . Enhanced Methanol Selectivity in CO₂ Hydrogenation by Decoration of K on MoS₂ Catalyst. Acta Physico-Chimica Sinica, 2024, 40(7): 2308017-0. doi: 10.3866/PKU.WHXB202308017
11. [11]
  Shi-Yu Lu , Wenzhao Dou , Jun Zhang , Ling Wang , Chunjie Wu , Huan Yi , Rong Wang , Meng Jin . Amorphous-Crystalline Interfaces Coupling of CrS/CoS₂ Few-Layer Heterojunction with Optimized Crystallinity Boosted for Water-Splitting and Methanol-Assisted Energy-Saving Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(8): 2308024-0. doi: 10.3866/PKU.WHXB202308024
12. [12]
  Wenwen Ma , Lian Kong , Jinyang Chu , Li Ma , Ziqing Ma , Heyu Cheng , Xinyuan Li , Zhan Yu , Zhen Zhao . Digitalization-Driven Olefin Production: Digital Design of Catalysts for CO₂-Assisted Oxidation Dehydrogenation of Ethane to Ethylene. University Chemistry, 2026, 41(1): 363-372. doi: 10.12461/PKU.DXHX202506055
13. [13]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . High-Stable Aqueous Zinc Metal Anodes Enabled by an Oriented ZnQ Zeolite Protective Layer with Facile Ion Migration Kinetics. Acta Physico-Chimica Sinica, 2025, 41(1): 100003-0. doi: 10.3866/PKU.WHXB202309003
14. [14]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
15. [15]
  Linhui Liu , Wuwan Xiong , Mingli Fu , Junliang Wu , Zhenguo Li , Daiqi Ye , Peirong Chen . Efficient NO_x abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange. Chinese Chemical Letters, 2024, 35(4): 108870-. doi: 10.1016/j.cclet.2023.108870
16. [16]
  Shihao Tan , Caiyun Cui , Shuwei Ma , Liangsen Zhu , Xianguo Liu . Introducing nanocrystalline/amorphous heterostructures on laminated FeSiBCr to synchronously enhance absorption, expand absorption bandwidth and reduce matching thickness. Acta Physico-Chimica Sinica, 2026, 42(7): 100283-0. doi: 10.1016/j.actphy.2026.100283
17. [17]
  Bin Liu . Teaching case design of chemistry “101 Plan” syntheticchemistry experiment course: taking the experiment of preparation of platinum nanocatalyst supported on carbon and determination of its electrochemical catalytic performance of methanol oxidation as an example. University Chemistry, 2026, 41(6): 125-135. doi: 10.12461/PKU.DXHX202506043
18. [18]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054
19. [19]
  Liangsen Zhu , Caiyun Cui , Tao Jing , Shihao Tan , Xianguo Liu , Menglin Yu . Strong and broadband microwave absorption under thin thickness induced by multiple dielectric relaxation and multiple magnetic resonances through the dual nanocrystalline phases in amorphous FeSiBCr flakes. Acta Physico-Chimica Sinica, 2026, 42(9): 100331-0. doi: 10.1016/j.actphy.2026.100331
20. [20]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020

Get Citation

PDF

XML

Metrics

PDF Downloads(21)
Abstract views(1893)
HTML views(487)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142