Citation: Li Mei QIU, Fen LIU, Liang Zhong ZHAO. Anodic Synthesis and Characterization of Na-Pb-O, Na-Pb-Bi-O Crystals[J]. Chinese Chemical Letters, ;2005, 16(1): 78-80. shu

Anodic Synthesis and Characterization of Na-Pb-O, Na-Pb-Bi-O Crystals

Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080

Received Date: 3 December 2003

Crystals of Na-Pb-O and Na-Pb-Bi-O were electrosynthesized on the anode from molten salts. The resulting crystals have a hexagonal structure, in which the base ions (Pb and Bi) are in high oxidation states. By using KOH/NaOH (atomic ratio K:Na=1:1) mixture as a flux,incorporation of K ions into the lattice is inhibited while incorporation of Bi ions is enhanced. The magnetic measurement shows that the Na-Pb-Bi-O crystals are dominated by diamagnetism.
- Lead complex oxides,
- anodic electrosynthesis,
- crystal growth,
- chacacterization.
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