Citation: ZHANG Rongben, XIE Zushou, WAN Youzhi, JIN Sunzhi, HOU Jianan. SYNTHESIS AND MESOMORPHIC PROPERTIES OF FISHBONE-LIKE LIQUID CRYSTALLINE POLYSILSESQUIOXANES——Ⅰ. FISHBONE-LIKE, β-DIKETONE-BASED LIQUID CRYSTALLINE POLYSILSESQUIOXANES AND THEIR COPPER COMPLEXES*[J]. Chinese Journal of Polymer Science, ;1993, 11(3): 210-219. shu

SYNTHESIS AND MESOMORPHIC PROPERTIES OF FISHBONE-LIKE LIQUID CRYSTALLINE POLYSILSESQUIOXANES——Ⅰ. FISHBONE-LIKE, β-DIKETONE-BASED LIQUID CRYSTALLINE POLYSILSESQUIOXANES AND THEIR COPPER COMPLEXES*

ZHANG Rongben ^{**，谢祖（王寿），万有志，金顺子，侯建安} ,
XIE Zushou ,
WAN Youzhi ,
JIN Sunzhi ,
HOU Jianan

Received Date: 19 March 1992

Two kinds of fishbone-like, β-diketone-based liquid crystalline polysilsesquioxanes(FBDKLCP'S), homopolymeric (H-FBDKLCP) and copolymeric (C-FBDKaLCP) have been first synthesized via the hydrosilylation reaction of a vinyl-terminated β-diketone with the homopolymeric ladderlike polyhydrosilsesquioxane (LPHSQ) and random copolymethylhydrosilsesquioxane (LRPMHSQ) respectively. These new kinds of FBDKLCP with M of 104 is thermotroic liquid crystalline polymer and its clearing temperatures Ti's and mesophase range △T's are much higher than those of the corresponding comb-like β-diketone liquid crystalline polysiloxane (DKLCP) by about 200℃.Similar results have been observed with the comparison of the two different structure Cu-coordinating compounds The significant increases in Tcl's and △T's of the FBDKLCP and Cu-FBDKLCP are mainly attributed to the great rigidity of the ladderlike polysilsesquioxane backbone.
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