Citation: Qian Wenhao, Huang Wei, Yufeng Cong. Aerobic Oxidation of Benzyl Alcohol catalyzed by CuBTC[J]. Chemistry, ;2019, 82(6): 555-558. shu

Aerobic Oxidation of Benzyl Alcohol catalyzed by CuBTC

College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001

Corresponding author: Huang Wei, yufengcong02@163.com
Received Date: 8 December 2018
Accepted Date: 18 February 2019

Figures(3)

Cu₃(BTC)₂ (BTC:1, 3, 5-benzenetricarboxylate) as cocatalyst is an effective and reusable heterogeneous catalyst, exhibiting enormous potential applications in heterogeneous catalysis. The CuBTC was evaluated for aerobic oxidation of benzylic alcohols in copper and TEMPO catalyst system. The aerobic oxidation of benzylic alcohols to aldehydes was performed with CuBTC catalyst. It is important that the catalyst system has a great selectivity and displays a preference for the primary versus secondary benzylalcohol. Comparison with copper acetate as a soluble, immobilization of the Cu(Ⅱ) in the rigid crystal structure of Cu₃(BTC)₂ does not diminish the intrinsic catalytic activity of this transition metal ion. But carboxylic acid can cause catalyst poisoning, therefore, CuBTC is not suitable for the reaction system in which carboxylic acid is present in raw materials, products or by-products.
- MOFs,
- CuBTC,
- Alcohol oxidation,
- Catalyst poisoning,
- Selectivity
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沈阳化工大学材料科学与工程学院沈阳 110142