Citation: Gui Bin MA, Julius GLASER. Novel Monomeric Phenanthroline-Thallium(Ⅲ) Complexes Multinuclear NMR Characterization in Organic Solvents[J]. Chinese Chemical Letters, ;2002, 13(7): 695-698. shu

Novel Monomeric Phenanthroline-Thallium(Ⅲ) Complexes Multinuclear NMR Characterization in Organic Solvents

Gui Bin MA ¹ ,
Julius GLASER ²

1.
Collcge of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006;
2.
Department of Chemistry, Royal Institute of Technology(KTH), S-100 44 Stockholm, Sweden

Received Date: 15 October 2001

A novel complex of monomeric thallium(Ⅲ) with the nitrogen donor ligand phenanthroline (phen) has been prepared and characterized by multinuclear NMR (¹H, ¹³C, ²⁰⁵Tl).The three complexes exist in equilibria in DMSO and acetonitrile solution, which was proved by the ²⁰⁵Tl NMR spectra. The ¹H and ¹³C NMR spectra of tris-phen Tl(Ⅲ) complex have been measured, where the spin-spin coupling between Tl (l=1/2) and ¹³C or ¹H signals were observed with the ¹H and ¹³C NMR spectroscopy in acetonitrile. The coupling constants are presented and the chemical shifts of complexes are discussed in detail.
- Thallium(Ⅲ),
- phenanthroline (phen),
- N-donor ligands,
- NMR spectroscopy
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