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Citation:
Zhi Zhou YUE, Yuan Chao LI. A Novel Synthesis of 3-O-Allyl-4, 5, 6-tri-O-benzyl-1-O-(p-methoxybenzyl)-D-myo-inositol[J]. Chinese Chemical Letters,
;2005, 16(2): 171-174.
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Highly efficient synthesis of the entitled compound was achieved from a readily available myo-inositol derivative. The key step involved a desymmetrization with (+)-camphor dimethyl ketal to give two diastereomers. The two diastereomers could be used to synthesize the same compound by changing the orders to introduce the protective groups.
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Keywords:
- Inositol,
- (+)-camphor dimethyl ketal,
- desymmetrization.
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