Citation: Zi Pin ZHANG, Bao Kang JIN, Yu Peng TIAN, Shi Jun WANG. Electrochemistry and In-situ Spectroelectrochemistry Studies of Carbazole and 9-Ethylcarbazole[J]. Chinese Chemical Letters, ;2005, 16(12): 1621-1624. shu

Electrochemistry and In-situ Spectroelectrochemistry Studies of Carbazole and 9-Ethylcarbazole

School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039

Received Date: 21 February 2005

Fund Project: We are grateful to the National Natural Science Foundation of China (No.20475001) for the financial support.

echanisms of electron transfer of carbazole (CZ) and 9-ethylcarbazole (ECZ) were studied by electrochemistry and in-situ spectroelectrochemistry. The result indicated that the electrochemical reaction mechanism of ECZ was the same as that of CZ. Both of them undergo ECE process: the initial step is removal of one electron to generate very reactive cation radical, this species then proceeded by deprotonation-coupling reaction to form the corresponding dimer, which was oxidized continuously.
- Carbazole,
- in-situ spectroelectrochemistry,
- cation radical
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