Citation: Xin Bin MA, Sheng Ping WANG, Hong Li GUO, Gen Hui XU. Preparation of Diphenyl Oxalate from Transesterification of Dimethyl Oxalate with Phenol over TS-1 Catalyst[J]. Chinese Chemical Letters, ;2003, 14(5): 461-464. shu

Preparation of Diphenyl Oxalate from Transesterification of Dimethyl Oxalate with Phenol over TS-1 Catalyst

State Key Laboratory of C₁ Chemistry and Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072

Received Date: 24 June 2002

Fund Project: This work was supported by the National Natural Science Foundation of China (20276050), Foundation for University Key Teacher by the Ministry of Education and the Department of Science and Technology of Yunnan Province for the project on Technology Collaboration and Development in China.

Diphenyl oxalate was synthesized from transesterification of dimethyl oxalate with phenol over TS-1( 2.5 wt% Ti ) catalyst.TS-1 catalyst, as a heterogeneous catalyst, showed excellent selectivity of diphenyl oxalate and methylphenyl oxalate compared with other homogeneous catalysts.Lewis acid sites on TS-1 catalyst were the active sites for transesterification of dimethyl oxalate with phenol.The high selectivity was closely related to the weak acid sites over TS-1.
- Diphenyl oxalate,
- transesterification,
- dimethyl oxalate,
- weak acid sites,
- TS
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