Citation: Mei Lei, Shi Weiqun. Construction Principles and Research Progress of Typical Actinide Supramolecular Assemblies[J]. Chemistry, ;2020, 83(5): 387-393. shu

Construction Principles and Research Progress of Typical Actinide Supramolecular Assemblies

Mei Lei ,
Shi Weiqun

Institute of High Energy Physics, Chinese Academy of Sciences, Beijing, 100049

Received Date: 18 December 2019
Accepted Date: 4 February 2020

Figures(4)

Actinide supermolecular chemistry is one of the recently emerging research areas of actinide chemistry, which can provide important information for the basic research of coordination chemistry of spent fuel reprocessing, and also explore the function and potential application of actinide functional materials in the fields of luminescence, catalysis, separation et al. This review will introduce recent progresses in actinide-based supramolecular assemblies. Starting from the construction principle of actinide-based supramolecular assemblies, and in combination with the author's own research works, the progresses of three typical kinds of actinide supramolecular assemblies including actinide-rotaxane complexes based on host-guest rotaxane ligands, actinide coordination complexes with closed structures and actinide supramolecular polymers based on supramolecular interactions are reviewed and summarized. We hope the paper can provide a reference for the design and synthesis of new actinide-based supramolecular assemblies in the future and promote the development of related fields of actinide chemistry and mateirals.
- Actinides,
- Supramolecular assembly,
- Coordination chemistry,
- Weak interactions
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