Citation: Wan Xuan ZHANG, Xue Long HOU. Addition of Allyltrimethylsilane to tert-Butanesulfinyl Imines Triggered by Tetra-n-butylammonium Fluoride[J]. Chinese Chemical Letters, ;2006, 17(8): 1037-1040. shu

Addition of Allyltrimethylsilane to tert-Butanesulfinyl Imines Triggered by Tetra-n-butylammonium Fluoride

Wan Xuan ZHANG ^1, ,
Xue Long HOU ²

1.
Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Faculty of Chemistry and Material Science, Hubei University, Wuhan 430062;
2.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032

Received Date: 24 February 2006

The addition of allyltrimethylsilane to tert-butanesulfinyl imines triggered by tetra-n-butylammonium fluoride (TBAF) in the presence of 4A molecular sieves has been studied, and homoallylsulfinamides were obtained in good yields with moderate to high diastereoselectivitics.
- Stereoselective addition,
- tert-butanesulfinyl imines,
- allyltrimethylsilane,
- tetra-n-butylammonium fluoride
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