Citation: Rui Fang GUAN, Chuan Jian ZHOU, Sheng Yu FENG, David J. BERG, Stephen R. STOBART. The Application of Suzuki Coupling Reaction on the Preparation of Carbosilane Dendrimers with 4-(Naphthalen-1-yl)phenyl Core[J]. Chinese Chemical Letters, ;2006, 17(3): 293-295. shu

The Application of Suzuki Coupling Reaction on the Preparation of Carbosilane Dendrimers with 4-(Naphthalen-1-yl)phenyl Core

1.
School of Chemistry, Shandong University, Ji'nan 250100;
2.
School of Materials Science and Engineering, Ji'nan University, Ji'nan 250022;
3.
School of materials science and Engineering, Shandong University, Ji'nan 250071;
4.
Department of Chemistry, University of Victoria, P. O. 3065, Victoria, B. C., Canada V8W 3P6

Received Date: 24 June 2005

Fund Project: The Project Sponsored by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (2005-55).

Carbosilane dendrimers with p-bromophenyl core were synthesized by alternating Grignard and hydrosilylation reaction. And the α-naphthalenyl was connected to the core by the Suzuki coupling reaction. A new carbosilane dendrimer with big π-conjugated structure[4-(naphthalen-1-yl)phenyl core] was given. It shows Suzuki coupling reaction is an effective and powerful core-functionalization method and the satisfactory result can be obtained through prolonging the reaction time with the increase of the generation of dendrimer.
- Suzuki coupling reaction,
- core functionalization,
- carbosilane,
- dendrimer,
- naphthalene
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