Citation: Ying Feng HAN, Ding Qiao YANG, Er Chang LIU, Jian Xia DONG. Rhodium-catalyzed Asymmetric Ring Opening Reaction of Oxabenzo-norbornadiene with Substituted Phenolic Nucleophiles[J]. Chinese Chemical Letters, ;2006, 17(3): 296-298. shu

Rhodium-catalyzed Asymmetric Ring Opening Reaction of Oxabenzo-norbornadiene with Substituted Phenolic Nucleophiles

College of Chemistry and Environment, South China Normal University, Guangzhou 510006

Received Date: 7 July 2005

Fund Project: We would like to thank the Natural Science Foundation of Guangdong Province for financial support (No.04010404).

We have developed an asymmetric ring opening reaction of oxabenzonorbornadienes with substituted phenolic nucleophiles. Under the reaction conditions ([Rh(COD)Cl]₂ (1 mol%), (S)-(R)-PPF-p^tBu₂ (2 mol%), THF, reflux), the reaction products were obtained with high yield and enantiomeric excesses (up to 99% ee).
- Asymmetric ring opening,
- rhodium-catalyzed,
- oxabenzonorbomadienes
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