Citation: LU Fagui, LIU Xi, CUI Yi, CHEN Liwei. Application of in-situ Characterization Techniques in Heterogenous Catalysis[J]. Chinese Journal of Catalysis, ;2019, 40(s1): 75-89. shu

Application of in-situ Characterization Techniques in Heterogenous Catalysis

LU Fagui ^1, ,
LIU Xi ^1,2 ,
CUI Yi ³ ,
CHEN Liwei ^1,3

1.
School of Chemistry and Chemical Engineering, In-situ Center for Physical Sciences, Shanghai Jiao Tong University, Shanghai 200240, China;
2.
Synfuels China Technology Co., Ltd, Beijing 101400, China;
3.
Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu, China

Fund Project: This work was supported by the National Natural Science Foundation of China (21625304, 21673273, 21872163).

As the science of catalysis develops with an unprecedented pace in recent years, the quest for new characterization techniques and methodologies to detect physicochemical properties of catalysts related to their catalytic performance and so attain insightful understanding of structure-activity relationship has become of crucial importance in both fundamental research and industrial applications. This review briefly summaries the developments of environmental transmission electron microscopy and in-situ X-ray spectroscopy techniques with emphasis on their applications in the characterization of nanocatalysts and complex surfaces and interfaces in heterogeneous catalysis. These examples confirm the pivotal importance of in-situ techniques in understanding the structure-activity relationship in catalysis and also in facilitating the design of highly efficient catalysts.
- catalyst,
- heterogeneous catalysis,
- in-situ characterization,
- transmission electron microscope,
- X-ray
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
51. [51]
52. [52]
53. [53]
54. [54]
55. [55]
56. [56]
57. [57]
58. [58]
59. [59]
60. [60]
61. [61]
62. [62]
63. [63]
64. [64]
65. [65]
66. [66]
67. [67]
68. [68]
69. [69]
70. [70]
71. [71]
72. [72]
73. [73]
74. [74]
75. [75]
76. [76]
77. [77]
78. [78]
79. [79]
80. [80]
81. [81]
82. [82]
83. [83]
84. [84]
85. [85]
86. [86]
87. [87]
88. [88]
89. [89]
90. [90]
91. [91]
92. [92]
93. [93]
94. [94]
95. [95]
96. [96]
97. [97]
98. [98]
99. [99]
100. [100]
101. [101]
102. [102]
103. [103]
104. [104]
105. [105]
106. [106]
107. [107]
108. [108]
109. [109]
110. [110]
111. [111]
112. [112]
113. [113]
114. [114]
115. [115]
116. [116]
117. [117]
118. [118]
119. [119]
120. [120]
121. [121]
122. [122]
123. [123]
124. [124]
125. [125]
126. [126]
127. [127]
128. [128]
129. [129]
130. [130]
131. [131]
132. [132]
133. [133]
134. [134]
135. [135]
136. [136]
137. [137]
138. [138]
139. [139]
140. [140]
141. [141]
142. [142]
143. [143]
144. [144]
145. [145]
146. [146]
147. [147]
148. [148]
149. [149]
150. [150]
151. [151]
152. [152]
153. [153]
154. [154]
155. [155]
156. [156]
157. [157]
158. [158]
159. [159]
160. [160]
161. [161]
162. [162]
163. [163]
164. [164]
165. [165]
166. [166]
167. [167]
168. [168]
169. [169]
170. [170]
171. [171]
172. [172]
173. [173]
174. [174]
175. [175]
176. [176]
177. [177]
178. [178]
179. [179]
180. [180]
181. [181]
182. [182]
183. [183]
184. [184]
185. [185]
186. [186]
187. [187]
188. [188]
189. [189]
190. [190]
191. [191]
192. [192]
193. [193]
194. [194]
195. [195]
196. [196]
197. [197]
198. [198]
199. [199]
200. [200]
201. [201]
202. [202]
203. [203]
204. [204]
205. [205]
206. [206]
207. [207]
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沈阳化工大学材料科学与工程学院沈阳 110142