Citation: Lin Fei XIAO, Jia Jian PENG, Chun Gu XIA. A Novel Method for Beckmann Rearrangement of Oximes with Silica Sulfuric Acid under Mild Condition[J]. Chinese Chemical Letters, ;2006, 17(5): 617-620. shu

A Novel Method for Beckmann Rearrangement of Oximes with Silica Sulfuric Acid under Mild Condition

State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences and Graduate School of Chinese Academy of Science, Lanzhou 730000

Received Date: 7 November 2005

Silica sulfuric acid in which sulfuric acid is immobilized on the surface of silica gel via covalent bond has been proved to be green catalyst for liquid-phase Beckmann rearrangement of oximes in dried dioxane at room temperature. Excellent conversion and selectivity were acquired in the Beckmann rearrangement of cyclohexanone oxime. The catalyst system was recycled and reused.
- Beckmann rearrangement,
- oximes,
- silica sulfuric acid
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