Citation: Youwei Xu, Fen Wang, Songjie Yu, Xingwei Li. Rhodium (III)-catalyzed selective access to isoindolinones via formal[4+1]annulation of arylamides and propargyl alcohols[J]. Chinese Journal of Catalysis, ;2017, 38(8): 1390-1398. shu

Rhodium (III)-catalyzed selective access to isoindolinones via formal[4+1]annulation of arylamides and propargyl alcohols

Youwei Xu ^a,b, ,
Fen Wang ^a ,
Songjie Yu ^a ,
Xingwei Li ^a

a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 25 June 2017
Revised Date: 30 June 2017

Fund Project: This work was supported by the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, and the National Natural Science Foundation of China (21525208, 21472186).

A mild and efficient oxidative synthesis of isoindolinones has been realized by Rh(Ⅲ)-catalyzed C-H activation of benzamides and[4 + 1] coupling with propargyl alcohols. This coupling system proceeds with broad substrate scope and mild conditions and provides a new approach to access the useful skeleton of γ-lactams with a stereogenic center.
- Rhodium,
- C-H activation,
- [4+1]annulation,
- Propargyl alcohol,
- Isoindolinones
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