Citation: Wen Fang SUN, Duo Yuan WANG. THE SYNTHESIS AND CHARACTERIZATION OF ANSYMMETRIC PENTAAZADENTATE PORPHYRIN-LIKE METAL COMPLEXES^*[J]. Chinese Chemical Letters, ;1993, 4(3): 225-228. shu

THE SYNTHESIS AND CHARACTERIZATION OF ANSYMMETRIC PENTAAZADENTATE PORPHYRIN-LIKE METAL COMPLEXES^*

Institute of Photographic Chemistry, Beijing, 100101

Received Date: 5 October 1992

This paper presents the synthesis and structural characterization of asymmetric tripyrrane-containing macrocycle.This macrocycle could be oxidized to the methine bridged,22 π-electron aromatic macrocyclic complexes containing cadmium(Ⅱ),samarium (Ⅲ),europium(Ⅲ)and gadolinium(Ⅲ)by treating with corresponding metal chloride in the presence of air Their structures were characterized by spectral methods.
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