Citation: Li Run, Shi Xiaofei, Jiang Qinyuan, Zhan Chenhao, Cui Yiming, Liu Qingxiong, He Ziying, Wei Fei, Zhang Rufan. Structure Control and Synthesis of Ultralong Carbon Nanotubes: Progress and Challenges[J]. Chemistry, ;2020, 83(7): 588-599. shu

Structure Control and Synthesis of Ultralong Carbon Nanotubes: Progress and Challenges

Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing, 100084

Corresponding author: Zhang Rufan, zhangrufan@tsinghua.edu.cn
Received Date: 28 February 2020
Accepted Date: 20 March 2020

Figures(9)

Carbon nanotubes (CNTs) have drawn intensive research interest in the past near 30 years due to their excellent properties and wide applications. In a large number of different types of CNTs, ultralong CNTs usually have perfect structures and lengths up to centimeters, even decimeters, showing extraordinary mechanical, electrical, and thermal properties. Ultralong CNTs are promising candidates for transparent displays, nanoelectronics, superstrong tethers, aeronautics and aerospace, etc. The controlled synthesis of ultralong CNTs with perfect structures is the key to fully exploit the extraordinary properties of CNTs. Over the past two decades, significant progress has been made in the study of ultralong CNTs, but there are also great challenges in controlled synthesis and mass production of ultralong CNTs, which limits their application. In this review, the progress on the growth mechanism, structure control, selective synthesis and extraordinary properties of ultralong CNTs and the innovative ideas in them is summarized. Meanwhile, the current challenges and future priorities were discussed. We hope that this review will shed light on the controlled synthesis, mass production and future application of ultralong CNTs and play a role in promoting the mass production and industrialization of ultralong CNTs with perfect structures.
- Ultralong carbon nanotubes,
- Synthesis,
- Property,
- Application
1. [1]
  Wehling T O, Black-Schaffer A M, Balatsky A V. Adv. Phys., 2014, 63(1):1~76.
2. [2]
  Zhang R, Zhang Y, Wei F. Chem. Soc. Rev., 2017, 46(12):3661~3715.
3. [3]
  Kong J, Soh H T, Cassell A M, et al. Nature, 1998, 395(6705):878~881.
4. [4]
  Cassell A M, Franklin N R, Tombler T W, et al. J. Am. Chem. Soc., 1999, 121(34):7975~7976.
5. [5]
  Kong J, Franklin N R, Zhou C W, et al. Science, 2000, 287(5453):622~625.
6. [6]
  Zhang Y, Chang A, Cao J, et al. Appl. Phys. Lett., 2001, 79(19):3155~3157.
7. [7]
  Kim W, Choi H C, Shim M, et al. Nano Lett., 2002, 2(7):703~708.
8. [8]
  Huang S, Cai X, Liu J. J. Am. Chem. Soc., 2003, 125(19):5636~5637.
9. [9]
  Zheng L X, O'Connell M J, Doorn S K, et al. Nat. Mater., 2004, 3(10):673~676.
10. [10]
  Ismach A, Kantorovich D, Joselevich E. J. Am. Chem. Soc., 2005, 127(33):11554~11555.
11. [11]
  Kocabas C, Shim M, Rogers J A. J. Am. Chem. Soc., 2006, 128(14):4540~4541.
12. [12]
  Jin Z, Chu H, Wang J, et al. Nano Lett., 2007, 7(7):2073~2079.
13. [13]
  Geblinger N, Ismach A, Joselevich E. Nat. Nanotechnol., 2008, 3(4):195~200.
14. [14]
  Wang X S, Li Q, Xie J, et al. Nano Lett., 2009, 9(9):3137~3141.
15. [15]
  Wen Q, Qian W, Nie J, et al. Adv. Mater., 2010, 22(16):1867~1871.
16. [16]
  Zhou W, Ding L, Yang S, et al. ACS Nano, 2011, 5(5):3849~3857.
17. [17]
  Liu J, Wang C, Tu X, et al. Nat. Commun., 2012, 3:1199.
18. [18]
  Zhang R, Zhang Y, Zhang Q, et al. ACS Nano, 2013, 7(7):6156~6161.
19. [19]
  Yang F, Wang X, Zhang D, et al. Nature, 2014, 510(7506):522~524.
20. [20]
  Hu Y, Kang L, Zhao Q, et al. Nat. Commun., 2015, 6:6099.
21. [21]
  Zhang S, Kang L, Wang X, et al. Nature, 2017, 543(7644):234~238.
22. [22]
  Bai Y, Zhang R, Ye X, et al. Nat. Nanotechnol., 2018, 13(7):589~595.
23. [23]
  Zhu Z, Wei N, Cheng W, et al. Nat. Commun., 2019, 10:4467.
24. [24]
  Huang S, Woodson M, Smalley R, et al. Nano Lett., 2004, 4(6):1025~1028.
25. [25]
  Wen Q, Zhang R, Qian W, et al. Chem. Mater., 2010, 22(4):1294~1296.
26. [26]
  Reina A, Hofmann M, Zhu D, et al. J. Phys. Chem. C, 2007, 111(20):7292~7297.
27. [27]
  Ding F, Harutyunyan A R, Yakobson B I. PNAS, 2009, 106(8):2506~2509.
28. [28]
  Flory P J. J. Am. Chem. Soc., 1936, 58:1877~1885.
29. [29]
  Zhang R, Xie H, Zhang Y, et al. Carbon, 2013, 52:232~238.
30. [30]
  Charlier J C. Acc. Chem. Res., 2002, 35(12):1063~1069.
31. [31]
  Choi H J, Ihm J, Louie S G, et al. Phys. Rev. Lett., 2000, 84(13):2917~2920.
32. [32]
  Krasheninnikov A V, Nordlund K, Sirvio M, et al. Phys. Rev. B, 2001, 63(24):245405.
33. [33]
  Sammalkorpi M, Krasheninnikov A, Kuronen A, et al. Phys. Rev. B, 2004, 70(24):245416.
34. [34]
  Chico L, Benedict L X, Louie S G, et al. Phys. Rev. B, Condens. Matter, 1996, 54(4):2600~2606.
35. [35]
  Charlier J, Ebbesen T W, Lambin P. Phys. Rev. B, Condens. Matter, 1996, 53:11108~11113.
36. [36]
  Zhu L, Wang J, Ding F. ACS Nano, 2016, 10(6):6410~6415.
37. [37]
  Xu Z, Yan T, Ding F. Chem. Sci., 2015, 6(8):4704~4711.
38. [38]
  Page A J, Ohta Y, Okamoto Y, et al. J. Phys. Chem. C, 2009, 113(47):20198~20207.
39. [39]
  Yuan Q, Xu Z, Yakobson B I, et al. Phys. Rev. Lett., 2012, 108(19):245505.
40. [40]
  Ding F. Phys. Rev. B, 2005, 72(24):245409.
41. [41]
  Liu Z, Jiao L, Yao Y, et al. Adv. Mater., 2010, 22(21):2285~2310.
42. [42]
  Chen Y, Zhang Y, Hu Y, et al. Adv. Mater., 2014, 26(34):5898~5922.
43. [43]
  Chen Y, Zhang J. Acc. Chem. Res., 2014, 47(8):2273~2281.
44. [44]
  Peng B, Yao Y, Zhang J. J. Phys. Chem. C, 2010, 114(30):12960~12965.
45. [45]
  Zhu Z, Wei N, Xie H, et al. Sci. Adv., 2016, 2(11):e1601572.
46. [46]
  Zhang R, Ning Z, Zhang Y, et al. Nat. Nanotechnol., 2013, 8(12):912~916.
47. [47]
  Wei C, Cho K, Srivastava D. Phys. Rev. B, 2003, 67(11):115407.
48. [48]
  Qian D, Wagner G J, Liu W K, et al. Appl. Mech. Rev., 2002, 55(6):495~533.
49. [49]
  Yu M, Lourie O, Dyer M J, et al. Science, 2000, 287(5453):637~640.
50. [50]
  Wu Y, Huang M, Wang F, et al. Nano Lett., 2008, 8(12):4158~4161.
51. [51]
  Chang C C, Hsu I K, Aykol M, et al. ACS Nano, 2010, 4(9):5095~5100.
52. [52]
  Peng B, Locascio M, Zapol P, et al. Nat. Nanotechnol., 2008, 3(10):626~631.
53. [53]
  Zhang R, Wen Q, Qian W, et al. Adv. Mater., 2011, 23(30):3387~3391.
54. [54]
  Wei N, Liu Y, Xie H, et al. Appl. Phys. Lett., 2014, 105(7):073107.
55. [55]
  Dienwiebel M, Verhoeven G S, Pradeep N, et al. Phys. Rev. Lett., 2004, 92(12):126101.
56. [56]
  Hirano M, Shinjo K. Phys. Rev. B, Condens. Matter, 1990, 41(17):11837~11851.
57. [57]
  Hirano M, Shinjo K, Kaneko R, et al. Phys. Rev. Lett., 1991, 67(19):2642~2645.
58. [58]
  Hong G, Zhou M, Zhang R, et al. Angew. Chem., Int. Ed., 2011, 50(30):6819~6823.
59. [59]
  Wang H, Liu J, Guo Z, et al. Nanoscale Microscale Thermophys. Eng., 2013, 17(4):349~365.
60. [60]
  Behabtu N, Young C C, Tsentalovich D E, et al. Science, 2013, 339(6116):182~186.
61. [61]
  Davis V A, Parra-Vasquez A N G, Green M J, et al. Nat. Nanotechnol., 2009, 4(12):830~834.
62. [62]
  Li Q, Zhang X, DePaula R F, et al. Adv. Mater., 2006, 18(23):3160~3163.
63. [63]
  Miyata Y, Shiozawa K, Asada Y, et al. Nano Res., 2011, 4(10):963~970.
64. [64]
  Franklin A D, Luisier M, Han S J, et al. Nano Lett., 2012, 12(2):758~762.
65. [65]
  Shulaker M M, Hills G, Patil N, et al. Nature, 2013, 501(7468):526~530.
66. [66]
  Tulevski G S, Franklin A D, Frank D, et al. ACS Nano, 2014, 8(9):8730~8745.
67. [67]
  Rutherglen C, Jain D, Burke P. Nat. Nanotechnol., 2009, 4(12):811~819.
68. [68]
  Cao Y, Brady G J, Gui H, et al. ACS Nano, 2016, 10(7):6782~6790.
1. [1]
  Ruilin He , Fengyi Wang , Zhikai Xia , Linling Zheng , Yue Liu . 球核酸的制备及DNA检测应用. University Chemistry, 2026, 41(5): 230-238. doi: 10.12461/PKU.DXHX202511108
2. [2]
  Lingqi Zhang , Hairong Huang , Jialin Li , Li Ji , Yufan Pan , Meiling Ye , Cuixue Chen , Shunü Peng . 桂花碳量子点的绿色制备及科普应用方案. University Chemistry, 2025, 40(8): 298-306. doi: 10.12461/PKU.DXHX202409138
3. [3]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
4. [4]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
5. [5]
  Qiuping Liu , Yongxian Fan , Wenxian Chen , Mengdi Wang , Mei Mei , Genrong Qiang . Design of Ideological and Political Education for the Preparation Experiment of Ferrous Sulfate. University Chemistry, 2024, 39(2): 116-120. doi: 10.3866/PKU.DXHX202309083
6. [6]
  Wenli FENG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress on ultralong room temperature phosphorescent carbon dots. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 833-846. doi: 10.11862/CJIC.20240308
7. [7]
  Wenyu Yuan , Ying Wang , Shuni Li , Xiaolin Zhu , Quanguo Zhai , Shengli Gao . Preparation and Purification of Alkali Metals. University Chemistry, 2026, 41(2): 218-231. doi: 10.12461/PKU.DXHX202502111
8. [8]
  Yufan Pan , Xue Ding , Jiayu Lin , Haiting Wu , Hairong Huang , Cuixue Chen , Meiling Ye . Oil Cosmetics, Charming Chemistry: A Gradient Science Popularization Scheme for Cream Cosmetic Preparation. University Chemistry, 2025, 40(4): 382-389. doi: 10.12461/PKU.DXHX202406078
9. [9]
  Cheng-an Tao , Jian Huang , Yujiao Li . Exploring the Application of Artificial Intelligence in University Chemistry Laboratory Instruction. University Chemistry, 2025, 40(9): 5-10. doi: 10.12461/PKU.DXHX202408132
10. [10]
  Jianna Peng , Hongjie Song , Lichun Zhang , Rui Liu , Yi Lü . Flow Cytometry: Principles, Applications, and Innovations in Spectroscopic Techniques. University Chemistry, 2026, 41(4): 231-238. doi: 10.12461/PKU.DXHX202506070
11. [11]
  Hong Zheng , Xin Peng , Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058
12. [12]
  Han WANG , Baihui CHEN , Chunlai WANG , Zhitao SHAO . Preparation and performance of lithium-sulfur battery of Ni₂P/carbon nanotube modified separator. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 933-943. doi: 10.11862/CJIC.20250334
13. [13]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
14. [14]
  Tiantian Zheng , Huiyi Wang , Huimin Li , Xuanhe Liu , Hong Shang . Anti-Counterfeiting National Salvation Chronicle of 006. University Chemistry, 2024, 39(9): 254-258. doi: 10.3866/PKU.DXHX202307032
15. [15]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-0. doi: 10.3866/PKU.WHXB202405016
16. [16]
  Lin′an CAO , Dengyue MA , Gang XU . Research advances in electrically conductive metal-organic frameworks-based electrochemical sensors. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 1953-1972. doi: 10.11862/CJIC.20250160
17. [17]
  Yu Liu , Pengfei Li , Yize Liu , Zaicheng Sun . Recent advances in carbon dots as a single photocatalyst. Acta Physico-Chimica Sinica, 2026, 42(2): 100167-0. doi: 10.1016/j.actphy.2025.100167
18. [18]
  Ben Yang , Shukun Shen , Pujun Jin , Yujia Luo , Jianyong Hu . Covalent organic frameworks: emerging organic porous materials. University Chemistry, 2026, 41(4): 264-274. doi: 10.12461/PKU.DXHX202502128
19. [19]
  Miaomiao He , Zhiqing Ge , Qiang Zhou , Jiaqing He , Hong Gong , Lingling Li , Pingping Zhu , Wei Shao . Exploring the Fascinating Realm of Quantum Dots. University Chemistry, 2024, 39(6): 231-237. doi: 10.3866/PKU.DXHX202310040
20. [20]
  Laiying Zhang , Yaxian Zhu . Exploring the Silver Family. University Chemistry, 2024, 39(9): 1-4. doi: 10.12461/PKU.DXHX202409015

Get Citation

PDF

XML

Metrics

PDF Downloads(30)
Abstract views(2775)
HTML views(629)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142