Citation: Chuan Fang ZHU, Hai Yan XIAO. TRIALKYL PHOSPHITES DIRECTLY CONVERTED TO DIALKYL ALKYLPHOSPHONATE IN THE ABSENCE OF ALKYL HALIDES[J]. Chinese Chemical Letters, ;1995, 6(7): 565-568. shu

TRIALKYL PHOSPHITES DIRECTLY CONVERTED TO DIALKYL ALKYLPHOSPHONATE IN THE ABSENCE OF ALKYL HALIDES

Department of Chemistry, Hua Zhong Normal University, Wuhan 430070

Received Date: 1 January 1995

By refluxing with cuprous halides in acetonitrile trialkyl phosphites can be directly converted into the corresponding dialkyl alkylphosphonate.The conversion of trialkyl phosphites with cuprous iodide is more favorable than with cuprous chloride;The activity of the alkyl group for the rearrangement is in the order of Me> Et> butyl.
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