Citation: Yun Kui LIU, Yong Min ZHANG. Synthesis of β-aminoesters and α-selenoesters via Active Metal Bismuth Produced by Sm/BiCl₃ System in Aqueous Media[J]. Chinese Chemical Letters, ;2000, 11(3): 195-198. shu

Synthesis of β-aminoesters and α-selenoesters via Active Metal Bismuth Produced by Sm/BiCl₃ System in Aqueous Media

Department of Chemistry, Zhejiang University at Xixi Campus, Hangzhou 310028

Received Date: 9 October 1999

Fund Project: We thank the National Natural Science Foundation of China (Project No.29872010 and 294938004),NSF of Zhejiang province, China and the Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Science for financial support.

Active metal bismuth is produced in situ via Sm/BiCl₃ system in aqueous media. Promoted by this active species,β-aminoesters and α-selenoesters are synthesized via reaction of α-bromoesters with 1-(a-aminoalkyl) benzotriazole and diselenides in moderate to good yields.
- Active metal bismuth,
- β-aminoesters,
- α-selenoesters,
- samarium,
- bismuth trichloride,
- aqueous media
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