Citation: Li Zeng PENG, Feng Zhi ZHANG, Tian Sheng MEI, Yu Lin LI. Studies on the Model Synthesis of the Brassinolide and Dolicholide Side Chains[J]. Chinese Chemical Letters, ;2003, 14(9): 889-892. shu

Studies on the Model Synthesis of the Brassinolide and Dolicholide Side Chains

National Laboratory of Applied Organic Chemistry, Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000

Received Date: 9 September 2002

Fund Project: This work was financially supported by the National Natural Science Foundation of China (Grant No.20072012) and the Special Research Grant for Doctoral Sites in Chinese Universities (Grant No.20010730001).

A stereoselective synthesis of brassinolide and dolicholide, which involves construction of the side chain enantiomers by a highly stereoselective aldol reaction of aldehyde 5 with the anion of α-silyloxy ketone 6 is described.
- Brassinolide,
- dolicholide,
- side chain,
- aldol reaction
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