Citation: Zhan Liang LIU, Jin Wang HUANO, Cai Lin LAO, Liang Nian JI. HYBRID ZINC(Ⅱ) AND IRON(Ⅲ)PORPHYRIN DIMER:A NEW MODEL SYSTEM OF CYTOCHROME P450 TO HYDROXYLATE CYCLOHEXANE[J]. Chinese Chemical Letters, ;1996, 7(1): 55-58. shu

HYBRID ZINC(Ⅱ) AND IRON(Ⅲ)PORPHYRIN DIMER:A NEW MODEL SYSTEM OF CYTOCHROME P450 TO HYDROXYLATE CYCLOHEXANE

1.
Department of Chemistry, Zhongshan University, Guangzhou, 510275;
2.
State Key Laboratory for OSSO, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou, 730001

Received Date: 29 May 1995

Fund Project: This work was supported by The National Natural Science Foundation of China and The Natural Science Foundation of Guangdong Province, China.

Hybrid zinc(Ⅱ) and iron(Ⅲ) porphyrin dimer,linked with a short flexible hydrocarbon chain(Fig.1),has been synthesized and characterized by EA,IR,¹H-NMR,XPS,and EPR spectroscopy.As a new model system of cytochrome P450,hybrid zinc(Ⅱ) and iron(Ⅲ) porphyrin dimer like iron(Ⅲ) porphyrin effectively catalyze hydroxylation of cyclohexane with molecular oxygen under mild conditions and catalytic activities of dimer are higher than those of iron(Ⅲ) porphyrin.Factors affecting catalytic activities are discussed from the point of view of partial intramolecular redox.
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