Citation: Qiu Tian LIU, Liang Ren HUANG. SYNTHESIS AND STRUCTURE OF A TRITHIOCARBONATO Mo(Et₄N)₂[(S₂)MO₂O₂(μ-S)₂(CS₃)][J]. Chinese Chemical Letters, ;1990, 1(2): 121-122. shu

SYNTHESIS AND STRUCTURE OF A TRITHIOCARBONATO Mo(Et₄N)₂[(S₂)MO₂O₂(μ-S)₂(CS₃)]

Fujian Institute of Research on the Structure of Matter and Fuzhou Laboratory of Structural Chemistry, Chinese Academy of Sciences, Fuzhou 350002

Fund Project: This work was supported by NNSFC.

A new trithiocarbonato Mo complex (Et₄N)₂ [(S₂)MO₂O₂(μ-S)₂(CS₃)] was obtained from a system containing MoO₄^2-,S_x^2-,and CS₂ and characterized by IR and X-ray structural analysis.The complex crystallizes in the monoclinic space group P2₁/c with a=9.539(3)Å,b=20.745(2)Å,c=15.452(2)Å,β=94.58(2)°,and Z=4.The structure was solved by direct and difference Fourier synthesis methods.Least squares refinement using 2910 reflections with I>3σ(I) converged to R=0.054.The CS₃^2- ligand in the complex chelates to Mo atom and values of the C-S bond distances in the CS₃^2- ligend indicate a substantial contribution of three resonance forms.
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