Citation: Zhong Biao ZHANG, Lian Sheng LI, Ru Yu CHEN, Qing Min WANG, Qiang ZENG. Synthesis of New Germanium Compounds Containing α-Amino AcidEster or α-Phosphonate Groups[J]. Chinese Chemical Letters, ;1997, 8(1): 9-10. shu

Synthesis of New Germanium Compounds Containing α-Amino AcidEster or α-Phosphonate Groups

Institute of Elemento-Organic Chemistry, State Key Laboratory of Elemento-Organic Chmisrty, Nankai University, Tianjin 300071

Received Date: 21 October 1996

Fund Project: This project is supported by the National Natural Science Foundation of China and by the State Key Laboratory of Elemento-Organic Chemistry.

A series of new type of germasesquioxides.germatranes,and β-trichlorogermylpropionic acid derivatives containing α-amino group or α-aminophosphonyl group were synthesized by a convenient condensation reaction of β-trichlorogermyl propionyl chloride with α-amino acid esters or α-phosphonates in the presense of organic base.The structures of products were determined by ¹HNMR.³¹PNMR,IR,MS,elemental analysis,and X-ray diffraction.
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