Citation: LI Hong, HE Binglin. POLYMER SUPPORT EFFECTS OF METAL COMPLEXES FOR CATALYSIS*[J]. Chinese Journal of Polymer Science, ;1998, 16(4): 362-369. shu

POLYMER SUPPORT EFFECTS OF METAL COMPLEXES FOR CATALYSIS*

LI Hong ,
HE Binglin

Received Date: 31 March 1998

In the course of investigating the catalytic behavior of metal complexes forring opening metathesis polymerization of cycloolefins, metathesis, hydroformylation andselective hydrogenation of olefins experimental results time and again indicate the pres-ence of effects of macromolecular supports -the utilization of macromolecular supportsincreases obviously the activity, selectivity, and stability of the catalysts and so as to in-crease the conversion of substrates, yields of reactions, properties of formed polymers and so on.Discussed these effects on the basis of the sythors'experiments.
1. [1]
  Xuebin Qiao , Lei Zhang . The role of bonding energy between atom, support and reactants in single atom catalysis. Chinese Chemical Letters, 2026, 37(6): 110998-. doi: 10.1016/j.cclet.2025.110998
2. [2]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
3. [3]
  Dong Sui , Jiayi Liu . Constriction-susceptible lithium support for fast cycling of solid-state lithium metal battery. Chinese Chemical Letters, 2025, 36(2): 110417-. doi: 10.1016/j.cclet.2024.110417
4. [4]
  Yunxia Liu , Guandong Wu , Lin Li , Yiming Niu , Bingsen Zhang , Botao Qiao , Junhu Wang . Construction of sintering-resistant gold catalysts via ascorbic-acid inducing strong metal-support interactions. Chinese Chemical Letters, 2025, 36(4): 110608-. doi: 10.1016/j.cclet.2024.110608
5. [5]
  Doudou Liu , Weiwei Guo , Guoliang Mei , Youpeng Dan , Rong Yang , Chao Huang , Yanling Zhai , Xiaoquan Lu . Application of catalyst Cu-t-ZrO₂ based on the electronic metal-support interaction in electrocatalytic nitrate reduction. Chinese Chemical Letters, 2025, 36(8): 110578-. doi: 10.1016/j.cclet.2024.110578
6. [6]
  Yinghui Pu , Yiming Niu , Tongtong Gao , Junnan Chen , Bingsen Zhang . Ammonia-directed gas-metal-support interaction forming Ni₃ZnN for efficient hydrogenation. Chinese Chemical Letters, 2026, 37(1): 111520-. doi: 10.1016/j.cclet.2025.111520
7. [7]
  Xiaoyu Zhao , Kai Gao , Sen Xue , Wei Ran , Rui Liu . Synergistic effects of oxygen vacancies and Pd single atoms on Pd@TiO_2−x for efficient HER catalysis. Chinese Chemical Letters, 2025, 36(6): 110309-. doi: 10.1016/j.cclet.2024.110309
8. [8]
  Jiaojiao Zhang , Yifan Wu , Yifei Li , Fuxing Lin , Shengchang Xiang , Xi Fan , Zhangjing Zhang . Molecular tweezers in thiolate-protected Cu(Ⅰ) clusters: A framework platform for investigating ligand effects in cluster catalysis. Chinese Chemical Letters, 2026, 37(6): 111003-. doi: 10.1016/j.cclet.2025.111003
9. [9]
  Xin Li , Xuan Ding , Junkun Zhou , Hui Shi , Zhenxi Dai , Jiayi Liu , Yongcun Ma , Penghui Shao , Liming Yang , Xubiao Luo . Utilizing synergistic effects of bifunctional polymer hydrogel PAM-PAMPS for selective capture of Pb(Ⅱ) from wastewater. Chinese Chemical Letters, 2024, 35(7): 109158-. doi: 10.1016/j.cclet.2023.109158
10. [10]
  Yuhuan Wu , Hoiian Ieong , Wenhao Wang , Chuanbin Wu , Anqi Lu , Xin Pan , Zhengwei Huang . Polymer modification effects in nanocarrier-loaded dissolving microneedles: Implications for transdermal drug delivery. Chinese Chemical Letters, 2026, 37(3): 111944-. doi: 10.1016/j.cclet.2025.111944
11. [11]
  Xue-Lu Ma , Jun-Bo Lu , Yuan Zhang , Ya-Fei Jiang , Jun Li . Dinitrogen fixation on transition metal complexes with flexible axial bonding. Chinese Journal of Structural Chemistry, 2026, 45(3): 100831-100831. doi: 10.1016/j.cjsc.2025.100831
12. [12]
  Zhihui ZONG , Zijie ZHAO , Lei HUANG , Zhicheng PAN , Shan WANG , Lili LIANG , Huaqing LIU , Enli ZHANG . Synthesis, crystal structures, and antitumor activity of two metal complexes of imidazolyl acylhydrazones. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 1048-1062. doi: 10.11862/CJIC.20250330
13. [13]
  Hongfei Li , Hao Chen , Qi Kang , Lihe Guo , Xingyi Huang , Haiping Xu . Gel polymer electrolyte for flexible and stretchable lithium metal battery: Advances and prospects. Chinese Chemical Letters, 2025, 36(9): 110325-. doi: 10.1016/j.cclet.2024.110325
14. [14]
  Gongxi Li , Jun Jin , Junxuan Tu , Haoguo Yue , Ying Wang , Xiaohui Jia , Weiyuan Yin , Zhenglin Han , Yuxuan Deng , Chunfeng Shi , Yonggang Zhen . Intrinsically stretchable polymer semiconductors synergistically constructed by hydrogen bonds and metal coordination. Chinese Chemical Letters, 2025, 36(12): 111716-. doi: 10.1016/j.cclet.2025.111716
15. [15]
  Panke Zhou , Hong Yu , Mun Yin Chee , Tao Zeng , Tianli Jin , Hongling Yu , Shuo Wu , Wen Siang Lew , Xiong Chen . Electron push-pull effects induced performance promotion in covalent organic polymer thin films-based memristor for neuromorphic application. Chinese Chemical Letters, 2024, 35(5): 109279-. doi: 10.1016/j.cclet.2023.109279
16. [16]
  Qiaojia GUO , Junkai CAI , Chunying DUAN . Effects of anions on the structural regulation of Zn-salen-modified metal-organic cage. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2203-2211. doi: 10.11862/CJIC.20240209
17. [17]
  Yuhao Guo , Na Li , Tingjiang Yan . Tandem catalysis for photoreduction of CO2 into multi-carbon fuels on atomically thin dual-metal phosphochalcogenides. Chinese Journal of Structural Chemistry, 2024, 43(7): 100320-100320. doi: 10.1016/j.cjsc.2024.100320
18. [18]
  Pengfu Gao , Yuan Geng , Wei Gong . Homochiral metal-organic frameworks bearing privileged ligands for heterogeneous asymmetric catalysis. Chinese Journal of Structural Chemistry, 2025, 44(10): 100719-100719. doi: 10.1016/j.cjsc.2025.100719
19. [19]
  Shili Wang , Mamitiana Roger Razanajatovo , Xuedong Du , Shunli Wan , Xin He , Qiuming Peng , Qingrui Zhang . Recent advances on decomplexation mechanisms of heavy metal complexes in persulfate-based advanced oxidation processes. Chinese Chemical Letters, 2024, 35(6): 109140-. doi: 10.1016/j.cclet.2023.109140
20. [20]
  Zhu Shu , Xin Lei , Yeye Ai , Ke Shao , Jianliang Shen , Zhegang Huang , Yongguang Li . ATP-induced supramolecular assembly based on chromophoric organic molecules and metal complexes. Chinese Chemical Letters, 2024, 35(11): 109585-. doi: 10.1016/j.cclet.2024.109585

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1465)
HTML views(32)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return