Citation: An Qi CHEN, Christine L. WILLIS. Unexpected Stereospecific Rearrangement-Addition Reaction of Trisubstituted Gibberellin Epoxides with Trimethylaluminium[J]. Chinese Chemical Letters, ;2001, 12(10): 855-858. shu

Unexpected Stereospecific Rearrangement-Addition Reaction of Trisubstituted Gibberellin Epoxides with Trimethylaluminium

An Qi CHEN ^1, ,
Christine L. WILLIS ²

1.
Department of Chemistry, Xiamen University, Xiamen 361005;
2.
School of Chemistry, University of Bristol, Bristol, UK BS8 1 TS

Received Date: 26 March 2001

Fund Project: This work is supported by the Ministry of Education under Scientific Research Foundation for Returned Overseas Chinese Scholars.

A novel rearrangement-addition reaction of trisubstituted gibberellin epoxides with trimethylaluminium is reported. The reaction proceeds stereospecifically to give tertiary methyl alcohols. The possible mechanism for the reaction is also discussed.
- Gibberellin,
- epoxide,
- trimethylaluminium,
- rearrangement-addition reaction
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