Citation: Yong JU, Yi CHEN, Yu Fen ZHAO. Differentiation Effect of Pentacoordinate Phosphorus on Carbohydrate Reaction[J]. Chinese Chemical Letters, ;1999, 10(5): 387-388. shu

Differentiation Effect of Pentacoordinate Phosphorus on Carbohydrate Reaction

Bioorganic Phosphorus Chemistry Laboratory, Department of Chemistry, Tsinghua University, Beijing 100084

Received Date: 26 November 1998

Fund Project: The authors thank the National Natural Science Foundation of China (No. 29672022) and Tsinghua University for financial supports.

The reaction between D-glucose. D-ribose and 2,2,2-trimethoxy-4,5-diphenyl-2,2-dihydro-1. 3. 2-dioxaphospholene were investigated by ³¹P NMR and FAB-MS. The results showed that there were a lot of differences in the reactions via pentacoordinate phosphorus compound. and it should give significant clue to the metabolism of carbohydrate phosphate in nature.
- Carbohydrate,
- pentacoordinate oxyphosphorane,
- biomimic mechanism
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