Citation: Guo Xiaosha, Chen Liangliang, Zhang Guanxin. Synthesis and Semiconducting Properties of 1, 4-Diketopyrrolopyrrole-based Conjugated Polymers with 2, 2, 6, 6-Tetramethyl-1-piperidinyloxyl Units in the Side Chains[J]. Chemistry, ;2020, 83(8): 711-717. shu

Synthesis and Semiconducting Properties of 1, 4-Diketopyrrolopyrrole-based Conjugated Polymers with 2, 2, 6, 6-Tetramethyl-1-piperidinyloxyl Units in the Side Chains

1.
Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190
2.
University of Chinese Academy of Sciences, Beijing, 100049

Corresponding author: Zhang Guanxin, gxzhang@iccas.ac.cn
Received Date: 9 March 2020
Accepted Date: 28 March 2020

Figures(6)

In this paper, the syntheses of two 1, 4-diketopyrrolopyrrole (DPP) based conjugated polymers, PDPP4T-1 and PDPP4T-2, in which the molar ratios of the 2, 2, 6, 6-tetramethyl-1-piperidinyloxyl (TEMPO) unit-contianing alkyl chains vs. branching alkyl chains are 1:5 and 1:10 and their semiconductor properties were reported. The test results indicated that introduction of TEMPO units in the alkyl side chains has almost no effect on their electronic configuration of polymer conjugated backbones. The thin films of PDPP4T-1 and PDPP4T-2 exhibit p-type semiconducting properties with hole mobilities up to 2.12 cm²·V^-1·s^-1, though lower than that of PDPP4T without TEMPO units in the alkyl side chains. Furthermore, their thin films were characterized with AFM and GIXRD to explore the possibilities for their performance variation.
- 2, 2, 6, 6-Tetramethyl-1-piperidinyloxy,
- 1, 4-Diketopyrrolopyrrole,
- Conjugated polymers,
- Organic field effect transistors
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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Semiconducting Properties of 1, 4-Diketopyrrolopyrrole-based Conjugated Polymers with 2, 2, 6, 6-Tetramethyl-1-piperidinyloxyl Units in the Side Chains

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com