Citation: Yu Peng TIAN, Jie Ying WU, Fu Xin XIE, Shi Sheng NI. New Complex Nonlinear optical Crystal-Bis(4-methoxybenzaldehyde thiosemicarbazone) Zinc Chloride(ZnL₂Cl₂)[J]. Chinese Chemical Letters, ;1998, 9(2): 215-217. shu

New Complex Nonlinear optical Crystal-Bis(4-methoxybenzaldehyde thiosemicarbazone) Zinc Chloride(ZnL₂Cl₂)

Yu Peng TIAN ^a,b ,
Jie Ying WU ^a,b ,
Fu Xin XIE ^a,b ,
Shi Sheng NI ^a,b

a Department of Chemistry, Anhui University, Hefei 230093;
b Coordination Chemistry Institute, State Key Laboratory of Nanjing University. Nanjing 210093

Received Date: 23 October 1997

Fund Project: This work was supported by the Natural Science Foundation of Anhui and the Educational Committee Foundation of Anhui.

The structure of ZnL₂Cl₂(L=4-methoxybenzaldehyde thiosemicarbazone) has been obtained by x-ray diffraction. The compound crystallized in space group Cc with Z=4, in a unit cell of dimensions, a=9.08909(10), b=22.1420(10), c=11.7890(10)Å; β=90.050(10)°, v=2374.6(12)Å³, Dc=1.552gcm^-3. μ=1.463mm^-1, R=0.0338, and Rw=0.0418. The structure contains individual ZnL₂Cl₂ distorted tetrahedral units in which L molecules are S-bonded as monodentate to the metal ions; chloride ions are also coordinated. The nonlinear optical properties of the zinc complex are also presented in this letter.
- zinc complex-nonlinear optical crystal,
- thiosemicarbazone derivative
1. [1]
  Shuangshuang GAI , Jixiang CAI , Moya YANG , Haijuan WU , Shuzhen FENG , Ming JIANG . Endoplasmic reticulum stress and mitochondrial apoptosis in thiosemicarbazone copper(Ⅱ) complex-triggered triple-negative breast cancer cell death. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 1073-1084. doi: 10.11862/CJIC.20250328
2. [2]
  Xuan Pang , Leyan Nian , Yongzhang Wang , Chunmei Huang . Na2(C6H4NO3)2∙H2O: A promising ultraviolet nonlinear optical crystal with strong second-harmonic generation effect and large birefringence. Chinese Journal of Structural Chemistry, 2026, 45(4): 100847-100847. doi: 10.1016/j.cjsc.2025.100847
3. [3]
  Jiming XI , Yukang TENG , Rui ZHANG , Zhenzhong LU . Fluorescent coordination polymers based on anthracene-and pyrene-derivative ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 847-854. doi: 10.11862/CJIC.20240367
4. [4]
  Jiajing Wu , Ru-Ling Tang , Sheng-Ping Guo . Three types of promising functional building units for designing metal halide nonlinear optical crystals. Chinese Journal of Structural Chemistry, 2024, 43(6): 100291-100291. doi: 10.1016/j.cjsc.2024.100291
5. [5]
  Lihua Gao , Yinglei Han , Chensheng Lin , Huikang Jiang , Guang Peng , Guangsai Yang , Jindong Chen , Ning Ye . Halogen-assisted octet binding electrons construction of pnictogens towards wide-bandgap nonlinear optical pnictides. Chinese Chemical Letters, 2024, 35(12): 109529-. doi: 10.1016/j.cclet.2024.109529
6. [6]
  Hongyuan Sha , Dongling Yang , Yanran Shang , Zujian Wang , Rongbing Su , Chao He , Xiaoming Yang , Xifa Long . Trithionic guanidine: A novel semi-organic short-wave ultraviolet nonlinear optical sulfate with dimeric heteroleptic tetrahedra. Chinese Chemical Letters, 2025, 36(4): 109730-. doi: 10.1016/j.cclet.2024.109730
7. [7]
  Yangfeifei Ou , Xiao-Liang Zhou , You-Zhao Lan , Jian-Wen Cheng . Borosilicates as deep-ultraviolet transparent nonlinear optical crystals: Structural motifs, performance limits and future directions. Chinese Journal of Structural Chemistry, 2025, 44(9): 100708-100708. doi: 10.1016/j.cjsc.2025.100708
8. [8]
  Yijia Chen , Wendan Luo , Ke Liu , Taihong Liu , Liping Ding , Yu Fang . Diverse roles of indacenodithiophene in push-pull chromophores for enhanced two-photon absorption and efficient nonlinear optical limiting. Chinese Journal of Structural Chemistry, 2025, 44(10): 100704-100704. doi: 10.1016/j.cjsc.2025.100704
9. [9]
  Ying Xu , Yan Pu , Qiong Zhang , Xi Kang , Manzhou Zhu . Order-by-order control over the nonlinear optical properties of atomically precise nanoclusters. Chinese Journal of Structural Chemistry, 2025, 44(10): 100735-100735. doi: 10.1016/j.cjsc.2025.100735
10. [10]
  Li Zhou , Fengyu Li , Zhou Lu , Yingwei Wang , Jun He . Two-dimensional atomic crystals for third-order nonlinear optical modulation. Chinese Journal of Structural Chemistry, 2026, 45(2): 100772-100772. doi: 10.1016/j.cjsc.2025.100772
11. [11]
  Le Ye , Zi-Luo Fang , Ming-Yu Guo , Wei-Xiong Zhang . Hot-pressing boosted nonlinear optical properties in a new ferroelectric plastic crystalline material. Chinese Chemical Letters, 2026, 37(4): 110826-. doi: 10.1016/j.cclet.2025.110826
12. [12]
  Yidan Chen , Yan Xiao , Yumiao Niu , Chu Chu , Ying Wang , Daqing Yang , Bingbing Zhang . Computer-aided search and targeted synthesis of infrared nonlinear optical materials in tin-containing sulfides. Chinese Journal of Structural Chemistry, 2026, 45(5): 100885-100885. doi: 10.1016/j.cjsc.2026.100885
13. [13]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
14. [14]
  Yuanjiao Liu , Xiaoyang Zhao , Songyao Zhang , Yi Wang , Yutuo Zheng , Xinrui Miao , Wenli Deng . Site-selection and recognition of aromatic carboxylic acid in response to coronene and pyridine derivative. Chinese Chemical Letters, 2024, 35(8): 109404-. doi: 10.1016/j.cclet.2023.109404
15. [15]
  An Lu , Yuhao Guo , Yi Yan , Lin Zhai , Xiangyu Wang , Weiran Cao , Zijie Li , Zhixia Zhao , Yujie Shi , Yuanjun Zhu , Xiaoyan Liu , Huining He , Zhiyu Wang , Jian-Cheng Wang . Nanomedicine integrating the lipidic derivative of 5-fluorouracil, miriplatin and PD-L1 siRNA for enhancing tumor therapy. Chinese Chemical Letters, 2024, 35(6): 108928-. doi: 10.1016/j.cclet.2023.108928
16. [16]
  Junying Zhang , Ruochen Li , Haihua Wang , Wenbing Kang , Xing-Dong Xu . Photo-induced tunable luminescence from an aggregated amphiphilic ethylene-pyrene derivative in aqueous media. Chinese Chemical Letters, 2024, 35(6): 109216-. doi: 10.1016/j.cclet.2023.109216
17. [17]
  Linlin Gan , Xuan Peng , Wenchao Zhai , Cheng Zhang , Xinyu Duan , Ke Deng , Wei Li , Qingdao Zeng . Regulatory effects of coronene and pyridine on the self-assembly structure of tetracarboxylic acid derivative formed by dimeric building blocks. Chinese Chemical Letters, 2026, 37(3): 110667-. doi: 10.1016/j.cclet.2024.110667
18. [18]
  Jie Niu , Xuan Wu , Jie Yu , Zhuo Lei , Ying-Ming Zhang , Li-Hua Wang , Yu Liu . Cucurbit[7]uril-confined cascade assembly of cyclodextrin phosphor derivative achieving multicolor delayed luminescence for information encryption. Chinese Chemical Letters, 2026, 37(5): 111419-. doi: 10.1016/j.cclet.2025.111419
19. [19]
  Ruiyan CHEN , Yanping HE , Jian ZHANG . Synthesis and third-order nonlinear optical property of Ti₄L₆ cage-based metal-organic framework. Chinese Journal of Inorganic Chemistry, 2025, 41(10): 2149-2156. doi: 10.11862/CJIC.20250177
20. [20]
  Yuwei Kang , Can Yang , Jun Zhang , Qi Wu . Synergistic triple-site engineering in ABX₃-type hybrid halides for high-performance nonlinear optical crystals. Chinese Chemical Letters, 2026, 37(1): 111385-. doi: 10.1016/j.cclet.2025.111385