Citation: Yuan Yin CHEN, Zhen Lin ZHONG, Yi Sui ZHOU, Bao Lian ZHANG, Xue Ran LU. Calixthiacrown:A New Multidentate Ligand for Platinum Metal[J]. Chinese Chemical Letters, ;1997, 8(3): 213-214. shu

Calixthiacrown:A New Multidentate Ligand for Platinum Metal

Department of Chemistry, Wuhan University, Wuhan 430072

Received Date: 4 November 1996

5,11,17,23-Tetra-tertbutyl-25,27-dihydroxy-26,28-1',7',13'-trioxa-4',10'-dithiatridecene calix[4]arene (Calix[4]dithiacrown-5) was synthesized from tetra-tert-butyl-calix[4]arene via 1,3-lower rim functionallization with chloroethyltosylate,followed by ring-closing condensation with β,β'-dimercaptoethyl ether in the presence of sodium ethoxide as a base under nitrogen atmosphere.It was found that the calix[4]dithiacrown-5 can form a platinum complex and the complex can catalyze the hydrosilylation of olefins with triethoxysilane efficiently.
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