Citation: Guo Xiang XU, Qi LU, Lei WEN, Ping HE. Chloro-propylene Sulfite as Electrolyte Additive for Li/S Batteries[J]. Chinese Chemical Letters, ;2006, 17(4): 557-560. shu

Chloro-propylene Sulfite as Electrolyte Additive for Li/S Batteries

Department of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871

Received Date: 15 July 2005

Chloro-propylene sulfite (ClPS) was employed as electrolyte additive of Li/S batteries for the first time. Linear potential sweep test showed that the ClPS keeps high electrochemical stability even under the voltage of 5.0V. Being used as electrolyte additive in Li/S batteries, ClPS displayed an excellent property for self-discharge prohibition. With ClPS additive the Li/S cells' initial discharge capacity was 856.2 mAh·g^-1 and 830.8 mAh·g^-1 at the current density of 15 mA·g^-1and 30 mA·g^-1, after 30 cycles the discharge capacities were contained at as high as 753.8 mAh·g^-1 and 715.6 mAh·g^-1. By means of infrared spectra, TG/DTA experiment and element content analysis the speculated reason of ClPS's novel function as additive was proposed.
- Chloro-propylene sulfite,
- Li/S battery,
- additive,
- self-discharge,
- capacity,
- cycle
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