Citation: Sun Shili, Zhang Hui, Yu Tianzhi, Zhao Yuling. Synthesis and Properties of A Coumarin-based Fluorescent Probe[J]. Chemistry, ;2020, 83(5): 448-452. shu

Synthesis and Properties of A Coumarin-based Fluorescent Probe

Sun Shili ¹ ,
Zhang Hui ¹ ,
Yu Tianzhi ^1,, ,
Zhao Yuling ²

1.
Key Laboratory of Opto-Electronic Technology and Intelligent Control(Ministry of Education), Lanzhou Jiaotong University
2.
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, 730070

Corresponding author: Yu Tianzhi, yutianzhi@hotmail.com
Received Date: 29 October 2019
Accepted Date: 8 December 2019

Figures(9)

A coumarin-based fluorescent probe L was synthesized. Its structure was characterized by NMR and MS. The probe has high selectivity and sensitivity towards Co²⁺ and Ni²⁺ in DMSO/water (v/v=9:1) solvent. Upon the addition of Co²⁺ or Ni²⁺, the probe L displayed remarkable fluorescence quenching, which could not be interfered by other metal ions. The results showed that the coordination ratio of probe L to Co²⁺ and Ni²⁺ is 1:2. The detection limits for Co²⁺ and for Ni²⁺ are 1.002×10^-7mol/L and 9.78×10^-6mol/L, and the binding constants are 1.06×10⁶ L·mol^-1 and 9.84×10⁵L·mol^-1, respectively.
- Coumarin,
- Fluorescent probe,
- Fluorescence quenching,
- Co²⁺,
- Ni²⁺
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