Citation: Fu Jiang DING, Liang Fu ZHANG. RELATIVE CONFORMER STABILITY OF OPEN-CHAIN PHOSPHANE:A PM3 STUDY[J]. Chinese Chemical Letters, ;1996, 7(3): 293-296. shu

RELATIVE CONFORMER STABILITY OF OPEN-CHAIN PHOSPHANE:A PM3 STUDY

Chengdu institute of organic Chemistry, Academia Sinica, Chengdu 610041

Received Date: 7 July 1995

Fund Project: This project was supported by National Natural Science Foundation of Chian.

The geometry and the energy of conformers of PnHn+2(n=2-9) have been studied with PM3 method.It is concluded that gauche interaction between adjacent lone electron pairs and gauche interaction between P-H bond with adjacent P-P bond are important for predicting the stable conformer of open-chain phosphoanes.
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