Citation: XIANG Yingxu, YE Cheng. NONLINEAR OPTICAL PROPERTIES OF A-SHAPED NITROPYRIMIDINE DERIVATIVES AND ITS POLYMERIC FILMS*[J]. Chinese Journal of Polymer Science, ;1996, 14(4): 362-367. shu

NONLINEAR OPTICAL PROPERTIES OF A-SHAPED NITROPYRIMIDINE DERIVATIVES AND ITS POLYMERIC FILMS*

XIANG Yingxu ,
YE Cheng

Received Date: 17 January 1996

Three A-shaped nitropyrimidine derivatives with benzyl or furfuryl as bridge havebeen synthesized. They possess shorter absorption wavelengths (λcut-off))-46 esu). The second order nonlinear optical coefficient d33 ofpoled BNPMOPMDA/PMMA doped film is 1.2-2.0×10-9 esu obtained by in-situ SHGmeasurements. It can be expected that the chromophore-functionalized polymer containinghigher number density of synthesized chromophore as side chain will be the potential blue-light transparent frequency doubling materials.
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