Citation: Wu Yu, Liu Jiacheng. Self-Assembled Dye-Sensitized Solar Cell Containing Dihydrothiazole Porphyrin Coordination Polymers[J]. Chemistry, ;2020, 83(8): 718-723. shu

Self-Assembled Dye-Sensitized Solar Cell Containing Dihydrothiazole Porphyrin Coordination Polymers

Wu Yu ^1, ,
Liu Jiacheng ²

1.
School of Chemistry and Chemical Engineering, Qiannan Normal University for Nationalities, Duyun, 558000
2.
College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, 730070

Received Date: 17 February 2020
Accepted Date: 12 May 2020

Figures(5)

Two new dihydrothiazole zinc porphyrin(2+2 type and A4 type) based Mn (Ⅱ) ion coordination polymers (CPsx, x=1, 2) have been synthesized and well-characterized. Two as-synthesized coordination polymers and anchored porphyrins (ZnPA) self-assembled into dye-sensitized solar cells through axial coordination of metal-ligands. The assemby modes of the assemblies immobilized on TiO₂ electrode surfaces were also verified by TEM. The photovoltaic performance tests showed that the self-assembly polymer has better photoelectric conversion efficiency than the monomer, especially the A4 type CPs2 based solar cell showed higher short circuit current and conversion efficiency. Their optical performance and EIS were also investigated to further understand the photoelectrochemical results.
- Dihydrothiazole,
- Porphyrin polymer,
- Self-assembly,
- Dye sensitized solar cells
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