Citation: Wang Peng, Li Lihua, Wu Xian, Ma Cheng. Research Progress of Polyoxometalate-Based Photocatalysts in the Dyes Photodegradation[J]. Chemistry, ;2019, 82(5): 415-423. shu

Research Progress of Polyoxometalate-Based Photocatalysts in the Dyes Photodegradation

Liaoning Shihua University, Fushun 113001

Corresponding author: Li Lihua, llh72@163.com
Received Date: 5 December 2018
Accepted Date: 25 December 2018

Figures(9)

How to effectively remove the dyes from the waste water has been the popular direction of materials and environmental science. Compared with traditional adsorption and concentration filtration methods, the photocatalytic degradation has attracted more attention due to its unique environmental-friendly, conveniency, safety and without secondary pollution. In numerous catalysts, heteropoly acid (HPA) has great potential in photocatalytic applications due to its special 'cage' structure, tunable electronic properties, non-toxicity, oxygen-rich surface, cheapness and excellent redox properties, etc. In this paper, the research progress of polyoxometalate-based photocatalysts in recent years was introduced, and they can be classified into two major categories:modification and loading method, which were further subdivided into substitution HPAs, altered counterion HPA, organic and inorganic modification method, silicate loading method, titanium dioxide loading method and graphene loading method. The main improvement direction is to resolve their water solubility problem, broaden the light response range, increase their specific surface area and improve the recyclability. The synthesis conditions and catalytic mechanism of different catalyst systems were summarized and analyzed in detail, at the end, the future development trend is forecasted.
- Dyes,
- Polyoxometalate-based catalysts,
- Photodegradation
1. [1]
  R Abe. J. Photoch. Photobio. A, 2010, 11(4):179~209.
2. [2]
  H Salavati, N Tavakkoli, M Hosseinpoor. Ultrason. Sonochem., 2012, 19(3):546~553.
3. [3]
  A Popa, V Sasca, O Verdes et al. React. Kinet. Mech. Cat., 2015, 115(1):355~375.
4. [4]
  P Lei, C Chen, J Yang et al. Environ. Sci. Techol., 2005, 39(21):8466~8474.
5. [5]
  S Antonaraki, E Androulaki, D Dimotikali et al. J. Photoch. Photobio. A, 2002, 148(1):191~197.
6. [6]
  M A Rauf, S B Bukallah, A Hamadi et al. Chem. Eng. J., 2007, 129(1):167~172.
7. [7]
  T Yamase. Chem. Rev., 1998, 98(1):307~326.
8. [8]
  N Mahmoodi, M Arami, M Limaee et al. J. Colloid Interf. Sci., 2006, 295(1):159~164.
9. [9]
  G Marcì, E García-López, L Palmisano et al. Appl. Catal. B, 2009, 90(3):497~506.
10. [10]
  R R Ozer, J L Ferry. Environ. Sci. Technol., 2001, 35(15):3242~3248.
11. [11]
  C Hu, B Yue, T Yamase. Appl. Catal. A, 2000, 194(6):99~107.
12. [12]
  T Yamase. Catal. Surv. Asia, 2003, 7(4):203~217.
13. [13]
  A Yan, S Yao, Y Li et al. Chem. Eur. J., 2014, 20(23):6927~6933.
14. [14]
  Y Kim, S Shanmugam. ACS Appl. Mater. Interf., 2013, 5(22):12197~12204.
15. [15]
  R Bauer, H Fallmann. Res. Chem. Intermediat., 1997, 23(4):341~354.
16. [16]
  Y Hua, C Wang, J Liu et al. J. Mol. Catal. A, 2012, 365(4):8~14.
17. [17]
  M Taghdiri, N Saadatjou, N Zamani et al. J. Hazard. Mater., 2013, 246~247(4):206~212.
18. [18]
  N Mirzaei, H R Ghaffari, K Sharafi et al. Chem. Eng. J., 2017, 5(4):3151~3160.
19. [19]
  Q Zhai, L Zhang, X Zhao et al. Appl. Surf. Sci., 2016, 377:17~22.
20. [20]
  B Fei, L Deng, J Wang et al. J. Hazard. Mater., 2017, 340:326~335.
21. [21]
  H Zhang, T Tong, W Cao et al. J. Sol-Gel Sci. Technol., 2015, 75(2):1~5.
22. [22]
  G R Bertolini, V Vetere, M A Gallo et al. Compt. Rendus Chim., 2016, 19(10):1174~1183.
23. [23]
  H R Ghalebi, S Aber, A Karimi et al. J. Mol. Catal. A, 2016, 415:96~103.
24. [24]
  S Hocine, C Rabia, M Bettahar et al. React. Kinet. Mech. Cat., 2003, 79(2):357~364.
25. [25]
  A Selloni. Nat. Mater., 2008, 7(8):613~615.
26. [26]
  W Zhou, M Cao, S Su et al. J. Mol. Catal. A, 2013, 371(5):70~76.
27. [27]
  T Li, Q Li, J Yan et al. Dalton Transac., 2014, 43(24):9061~9069.
28. [28]
  H Shi, T Zhang, T An et al. J. Colloid Interf. Sci., 2012, 380(1):121~127.
29. [29]
  A Olgun, A T Çolak, I·H Gübbük et al. J. Mol. Struct., 2017, 1134:78~84.
30. [30]
  K Lv, Y Xu. J. Phys. Chem. B, 2006, 110(12):6204~6212.
31. [31]
  W Wang, L Xu, G Gao et al. Inorg. Chem. Commun., 2009, 12(3):259~262.
32. [32]
  X Liu, J Luo, Y Zhu et al. J. Alloy Compd., 2015, 648:986~993.
33. [33]
  X Liu, W Gong, J Luo et al. Appl. Surf. Sci., 2016, 362:517~524.
34. [34]
  M Liu, X Yang, F Zhu et al. Dalton Transac., 2018, 47(15):5245~5251.
35. [35]
  X Fan, Y Guo, H Lv et al. Dalton Transac., 2018, 47(21):115~132.
36. [36]
  A Balaska, E H Samar, A Grid et al. Desalin. Water Treat., 2015, 54(2):382~392.
37. [37]
  G Gao, F Li, L Xu et al. J. Am. Chem. Soc., 2008, 130(33):10838~10839.
38. [38]
  Y Gong, Y Guo, Q Hu et al. ACS Sustain. Chem. Eng., 2017, 5(5):4521~4530.
39. [39]
  K Lv, Y Xu. J. Phys. Chem. B, 2006, 110(12):6204~6212.
40. [40]
  Y Zhou, G Chen, Z Long et al. RSC Adv., 2014, 4:42092~42113.
41. [41]
  S Farhadi, M Amini, F Mahmoudi et al. RSC Adv., 2016, 6(105):102984~102996.
42. [42]
  A Kubacka, M Fernandez-Garcia, G Colon. Chem. Rev., 2016, 112(3):1555~1614.
43. [43]
  Y Hou, J Ma, T Wang et al. Mat. Sci. Semicon. Proc., 2015, 39:229~234.
44. [44]
  H Li, S Gao, M Cao et al. J. Colloid Interf. Sci., 2013, 394(1):434~440.
45. [45]
  C Xue, J Xia, T Wang et al. Mater. Lett., 2014, 133:274~277.
46. [46]
  Q Wang, T Niu, D Jiao et al. New J. Chem., 2017, 41(11):1010~1039.
47. [47]
  T Kyotani, T Nagai, A Sanjuro Inoue et al. Chem. Mater., 2014, 9(2):609~615.
48. [48]
  L Shi, T Wang, H Zhang et al. Adv. Sci., 2015, 2(3):150006~150014.
49. [49]
  H Park, W Cho. J. Phys. Chem. B, 2003, 107(16):3885~3890.
50. [50]
  N Dimitrijevic, M Savic, D Micic et al. Chem. Informat., 1984, 15(51):4278~4283.
51. [51]
  S Cong, Y Xu. J. Hazard. Mater., 2011, 192(2):485~489.
52. [52]
  S S Wang, G Y Yang. Chem. Rev., 2015, 115(11):4893~4901.
53. [53]
  R Contant, J P Ciabrini. Chem. Informat., 1977, 8(50):123~142.
54. [54]
  J Kim, J Kim. Environ. Sci. Technol., 2014, 48(22):13384~13391.
55. [55]
  C Chen, P Lei, H Ji et al. Environ. Sci. Technol., 2004, 38:329~337.
56. [56]
  L Xu, X Yang, Y Guo et al. J. Hazard. Mater., 2010, 178(1/3):1070~1077.
57. [57]
  H Shi, T Zhang, T An et al. J. Colloid Interf. Sci., 2012, 380(1):121~127.
58. [58]
  C H Liang, F B Li, C S Liu et al. Dyes Pigments, 2008, 76(2):477~484.
59. [59]
  J Thomas, S Radhika, M Yoon. Mol. Catal., 2017, 433:274~281.
60. [60]
  A Proust, B Matt, R Villanneau et al. Chem. Soc. Rev., 2012, 41(22):7605~7622.
61. [61]
  N Dubey, S S Rayalu, N K Labhsetwar et al. Appl. Catal. A, 2006, 303:152~157.
62. [62]
  R Chatti, S S Rayalu, N Dubey et al. Sol. Energ. Mater. Sol. Cell, 2007, 91(2):180~190.
63. [63]
  C G Lin, J Hu, Y F Song. Adv. Inorg. Chem., 2017, 8(3):776~789.
64. [64]
  S Nardecchia, D Carriazo, M L Ferrer et al. Chem. Soc. Rev., 2013, 42(2):794~830.
65. [65]
  T F Yeh, J M Syu, C Cheng et al. Adv. Funct. Mater., 2010, 20(14):2255~2262.
66. [66]
  S Nardecchia, D Carriazo, M Ferrer et al. Chem. Soc. Rev., 2013, 42(2):794~830.
67. [67]
  H Fakhri, A R Mahjoub, H Aghayan. Chem. Eng. Res. Des., 2017, 120:303~315.
68. [68]
  J Liu, Y Liu, N Liu et al. Science, 2015, 46(23):970~974.
69. [69]
  Y Liu, F Luo, S Liu et al. Small, 2017, 13(14):160~174.
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