Citation: CAO Weixiao, HAN Ping, FENG Xinde. STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES[J]. Chinese Journal of Polymer Science, ;1983, 1(2): 189-195. shu

STUDIES ON CHARGE TRANSFER POLYMERIZATION——POLYMERIZATION OF ACRYLONITRILE INITIATED WITH PHENYL HYDRAZINE AND ITS DERIVATIVES

Received Date: 7 July 1983

The photopolymerization of acrylonitrile (AN) initiated with phenyl hydrazine (PHZ) and its derivatives has been studied. The initiator exponent and monomer exponent were determined from the kinetic investigation to be 0.66th and 2.1th respectively and the overall activation energy was 33.4KJ/mol for the PHZ-AN system. Spectral analysis and other data indicate that a charge transfer complex between PHZ as a donor and AN as an aceeptor is formed. The initiation mechanism was proposed.
1. [1]
  Xiang Li , Beibei Zhang , Zhixiang Wang , Xiangyu Chen . Organocatalyzed iodine-mediated reversible-deactivation radical polymerization via photoinduced charge transfer complex catalysis. Chinese Chemical Letters, 2025, 36(6): 110383-. doi: 10.1016/j.cclet.2024.110383
2. [2]
  Bing Niu , Honggao Huang , Liwei Luo , Li Zhang , Jianbo Tan . Coating colloidal particles with a well-defined polymer layer by surface-initiated photoinduced polymerization-induced self-assembly and the subsequent seeded polymerization. Chinese Chemical Letters, 2025, 36(2): 110431-. doi: 10.1016/j.cclet.2024.110431
3. [3]
  Jian Song , Shenghui Wang , Qiuge Liu , Xiao Wang , Shuo Yuan , Hongmin Liu , Saiyang Zhang . N-Benzyl arylamide derivatives as novel and potent tubulin polymerization inhibitors against gastric cancers: Design, structure–activity relationships and biological evaluations. Chinese Chemical Letters, 2025, 36(2): 109678-. doi: 10.1016/j.cclet.2024.109678
4. [4]
  Jingfeng Yue , Zhenxin Tang , Yuxing Zhang , Zhongbao Jian . Oligomeric α-diimine nickel catalysts for enhanced ethylene polymerization. Chinese Chemical Letters, 2026, 37(1): 111930-. doi: 10.1016/j.cclet.2025.111930
5. [5]
  Hailong He , Wenbing Wang , Wenmin Pang , Chen Zou , Dan Peng . Double stimulus-responsive palladium catalysts for ethylene polymerization and copolymerization. Chinese Chemical Letters, 2024, 35(7): 109534-. doi: 10.1016/j.cclet.2024.109534
6. [6]
  Feng Shi , Guiling Li , Haibing Zhu , Ling Li , Ming Chen , Juan Li , Huifang Shen , Hao Zeng , Lingfeng Min , Zhanjun Yang . Nanozyme-triggered polymerization amplification strategy for constructing highly sensitive surface plasmon resonance immunosensing. Chinese Chemical Letters, 2025, 36(6): 110333-. doi: 10.1016/j.cclet.2024.110333
7. [7]
  Chaojian Xu , Juxin Yin , Sihong Wang , Yue Pan , Qianhe Zhang , Ningkang Xie , Shuo Yang , Shaowu Lv . Aerobic radical polymerization of hydrogels triggered by acetylacetone-transition metal self-initiation. Chinese Chemical Letters, 2025, 36(7): 111075-. doi: 10.1016/j.cclet.2025.111075
8. [8]
  Jiarong Li , Shude Liu , Yuanzhao Xie , Yue Sun , Zhuyu Liu , Meihua Chen , Yaobang Li , Yonghui Deng . Nanoemulsion-assisted assembly and polymerization towards core-shell magnetic mesoporous melamine-formaldehyde resin microspheres. Chinese Chemical Letters, 2026, 37(4): 111433-. doi: 10.1016/j.cclet.2025.111433
9. [9]
  Zhaojun Chen , Yongqi Wang , Yongshun Liang , Liang Shan , Ying Wang , Jiyue Hou , Ziyi Zhu , Xue Li , Yiyong Zhang . In-situ polymerization technology for all-solid state lithium batteries: Current status and future development. Chinese Chemical Letters, 2026, 37(6): 112020-. doi: 10.1016/j.cclet.2025.112020
10. [10]
  Qiuyun Li , Yannan Zhu , Yining Wang , Gang Qi , Wen-Juan Hao , Kelu Yan , Bo Jiang . Catalytic CH activation-initiated transdiannulation: An oxygen transfer route to ring-fluorinated tricyclic γ-lactones. Chinese Chemical Letters, 2024, 35(9): 109494-. doi: 10.1016/j.cclet.2024.109494
11. [11]
  Xue Zhao , Mengshan Chen , Dan Wang , Haoran Zhang , Guangzhi Hu , Yingtang Zhou . Ultrafine nano-copper derived from dopamine polymerization & synchronous adsorption achieve electrochemical purification of nitrate to ammonia in complex water environments. Chinese Chemical Letters, 2024, 35(8): 109327-. doi: 10.1016/j.cclet.2023.109327
12. [12]
  Heng Gao , Zhaocong Cheng , Guangshui Tu , Zonglin Qiu , Xieyi Xiao , Haotian Zhou , Handou Zheng , Haiyang Gao . Thermally robust bis(imino)pyridyl iron catalysts for ethylene polymerization: Synergy effects of weak π-π interaction, steric bulk, and electronic tuning. Chinese Chemical Letters, 2025, 36(5): 110762-. doi: 10.1016/j.cclet.2024.110762
13. [13]
  Hongen Cao , Xinrui Xiao , Xu Zhang , Yiyang Zhang , Lei Yu . Element Transfer Reaction theory: Scientific connotation and its applications in chemical industry. Chinese Chemical Letters, 2025, 36(9): 110924-. doi: 10.1016/j.cclet.2025.110924
14. [14]
  Hui Lei , Yingying Jiang , Jiayu Liu , Weifeng Zhang , Fanbo Meng , Jun Mou , Wenyi Liu , Pengcheng Lei , Rui Xiong , Zan Xu , Hang Zhang , Yanjun Wang , Guo-Bo Li , Lingling Yang , Hua-Li Wang . Structure-activity relationship studies of 3,4-disubstitued indole-2-ketone derivatives identify a potent glutaminyl cyclase inhibitor with antitumor activity against breast cancer. Chinese Chemical Letters, 2026, 37(6): 111511-. doi: 10.1016/j.cclet.2025.111511
15. [15]
  Fei Yin , Erli Yang , Xue Ge , Qian Sun , Fan Mo , Guoqiu Wu , Yanfei Shen . Coupling WO₃₋_x dots-encapsulated metal-organic frameworks and template-free branched polymerization for dual signal-amplified electrochemiluminescence biosensing. Chinese Chemical Letters, 2024, 35(4): 108753-. doi: 10.1016/j.cclet.2023.108753
16. [16]
  Lei Li , Guang Yang , Tianbai Xiong , Tingzhu Duan , Jia Wang , Xin Wang . Metal-free click polymerization of thiols and chalcone-derived internal olefins in air to prepare functional clusteroluminescent polythioethers for dual-response fluorescent probe. Chinese Chemical Letters, 2025, 36(11): 111374-. doi: 10.1016/j.cclet.2025.111374
17. [17]
  Man Xu , Qianyi Li , Jingyao Ma , Hao Li , Yunfei Zhu , Fan Yu , Kuande Wang , Tao Zhou , Quanyou Feng , Linghai Xie , Jinyi Lin . Wide bandgap steric carbazole-fluorene-nanogrid polymers via metal-free CN polymerization for deep-blue polymer light-emitting diodes. Chinese Chemical Letters, 2026, 37(1): 111551-. doi: 10.1016/j.cclet.2025.111551
18. [18]
  Hao Liu , Pin Zhao , Yao Jiang , Subo Xu , Weilong Song , Xinhua Wang . Influence of the interlayer properties on the thin-film composite membrane performance based on UiO-66 and its derivatives. Chinese Chemical Letters, 2026, 37(5): 111862-. doi: 10.1016/j.cclet.2025.111862
19. [19]
  Yadong Li , Feng-Huan Du , Junjie Li , Jun Xu , Zhifang Yang , Shanshan Li , Chi Zhang , Yunfei Du . Preparation of benziodazole-triflate and its application as both 2-iodobenzamido- and triflate-transfer reagents. Chinese Chemical Letters, 2025, 36(6): 110338-. doi: 10.1016/j.cclet.2024.110338
20. [20]
  Yihu Ke , Shuai Wang , Fei Jin , Guangbo Liu , Zhiliang Jin , Noritatsu Tsubaki . Charge transfer optimization: Role of Cu-graphdiyne/NiCoMoO4 S-scheme heterojunction and Ohmic junction. Chinese Journal of Structural Chemistry, 2024, 43(12): 100458-100458. doi: 10.1016/j.cjsc.2024.100458

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1748)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return