Citation: Rui Xue LIU, Yan SHI, Zhi Feng FU, Shu Ke JIAO. Synthesis of Highly Branched Poly(ε-caprolactone) by Self-condensing Atom Transfer Radical Polymerization of Macroinimers[J]. Chinese Chemical Letters, ;2006, 17(3): 373-376. shu

Synthesis of Highly Branched Poly(ε-caprolactone) by Self-condensing Atom Transfer Radical Polymerization of Macroinimers

Key Laboratory of Science and Technology of Controllable Chemical Reactions Ministry of Education, Beijing University of Chemical Technology, Beijing 100029

Received Date: 22 August 2005

Branched poly(ε-caprolactone) was synthesized by self-condensing atom transfer radical polymerization of macroinimer, α-acryloyoxy-ω-2-bromopropionyloxy poly(ε-caprolactone), which was prepared by enzyme-catalyzed ring-opening polymerization of ε-caprolactone with 2-hydroxylethyl acrylate as initiator and esterification of the ω-hydroxyl group of the obtained poly(ε-caprolactone) by 2-bromopropionyl bromide.
- Self-condensing vinyl polymerization,
- atom transfer radical polymerization,
- branched polymers,
- poly(ε-caprolactone)
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