Citation: Zhao Lingyu, Wang Jiaojiao, Gao Wenhui. Preparation of Cyhalothrin Molecularly Imprinted Solid-Phase Extraction Membrane and Its Application in Food Detection[J]. Chemistry, ;2019, 82(1): 80-86. shu

Preparation of Cyhalothrin Molecularly Imprinted Solid-Phase Extraction Membrane and Its Application in Food Detection

College of Biological Science and Engineering, Hebei University of Science and Technology; Center for Fermentation Engineering of Hebei Province, Shijiazhuang 050000

Corresponding author: Gao Wenhui, wenuigao@126.com
Received Date: 28 June 2018
Accepted Date: 26 September 2018

Figures(7)

A molecularly imprinted solid phase extraction membrane with high selectivity to pyrethroid was prepared by in situ polymerization using cyhalothrin as template molecule, ethylene glycol dimethacrylate as the cross linking agent and acetonitrile as porogenic agent, and the performance and application of as-prepared molecularly imprinted membrane were investigated. Ultraviolet spectroscopy was used to study the selection of functional monomer and the concentration ratio of functional monomer to template molecule. This molecularly imprinted membrane was used to enrich and cleanse pyrethrin pesticide residues in samples. The results showed that the membrane had strong specific adsorption and enrichment capacity for pyrethrin pesticides. The detection limits were 0.01μg/mL for cyhalothrin and bifenthrin, 0.05μg/mL for tetramethrin, beta cypermethrin, dimefluthrin and fenvalerate. The average recoveries of the spiked samples were between 83.4% and 95.9%, the relative standard deviations were 1.45%~3.76% (n=5). The method is simple, sensitive, accurate and reliable.
- Cyhalothrin,
- Pyrethrin pesticide,
- Molecularly imprinted solid phase extraction membrane
1. [1]
2. [2]
3. [3]
  X Yang, H Zhang, Y Liu et al. Food Chem., 2011, 127(2): 855~865.
4. [4]
  M Arvand, E Bozorgzadeh, S Shariati. J. Food Composit. Anal., 2013, 31(2): 275~283.
5. [5]
  H Haddadi, M Shirani, A Semnani et al. Chromatographia, 2014, 77(9/10): 715~721.
6. [6]
  K Wang, X Xie, Y Zhang et al. Food Chem., 2018, 240: 1233~1242.
7. [7]
  D Šatínský, D Kameníčková, P Chocholouš et al. Chromatographia, 2013, 76(21~22): 1559-1564.
8. [8]
  U Koesukwiwat, S J Lehotay, N Leepipatpiboon. J. Chromatogr. A, 2011, 1218(39): 7039~7050.
9. [9]
  D Paradis, G Bérail, J M Bonmatin et al. Anal. Bioanal. Chem., 2014, 406(2): 621~633.
10. [10]
11. [11]
12. [12]
  F David, C Devos, E Dumont et al. Talanta, 2017, 165: 201~210.
13. [13]
14. [14]
15. [15]
  S Fang, B Zhang, K W Ren et al. J. Agr. Food Chem., 2011, 59(5): 1594~1597.
16. [16]
17. [17]
18. [18]
  T Du, J Cheng, M Wu et al. J. Chromatogr. B, 2014, 951: 104~109.
19. [19]
20. [20]
  L Chen, X Wang, W Lu et al. Chem. Soc. Rev., 2016, 45(8): 2137~2211.
21. [21]
  X J Chen, J Wang, Y X She et al. J. Food Saf. Qual., 2014, 5(5): 1459~1467.
22. [22]
23. [23]
1. [1]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
2. [2]
  Siwei Hou , Yaxin Niu , Guanglu Zhang , Yanmei Yang , Xu Wang , Zhenzhen Chen . Application of Solid-Phase Microextraction and Mass Spectrometry in Environmental Detection. University Chemistry, 2026, 41(3): 297-306. doi: 10.12461/PKU.DXHX202504078
3. [3]
  Yuxia Luo , Xiaoyu Xie , Fangfang Chen . 药物递送魔法师——分子印迹聚合物. University Chemistry, 2025, 40(8): 202-210. doi: 10.12461/PKU.DXHX202409129
4. [4]
  Shahua Huang , Xiaoming Guo , Lin Lin , Guangping Chang , Sheng Han , Zuxin Zhou . Application of “Integration of Industry and Education” in Engineering Chemistry: Improvement of the Pesticide Fipronil Production. University Chemistry, 2024, 39(3): 199-204. doi: 10.3866/PKU.DXHX202309064
5. [5]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
6. [6]
  Yuxia Gao , Li Zhang , Chenhui Zhang , Fengpei Du . Chemical Empowerment for Green Development of Pesticides: From Molecular Design to Field Application. University Chemistry, 2025, 40(12): 78-86. doi: 10.12461/PKU.DXHX202509052
7. [7]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
8. [8]
  Yiping HUANG , Liqin TANG , Yufan JI , Cheng CHEN , Shuangtao LI , Jingjing HUANG , Xuechao GAO , Xuehong GU . Hollow fiber NaA zeolite membrane for deep dehydration of ethanol solvent by vapor permeation. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 225-234. doi: 10.11862/CJIC.20240224
9. [9]
  Shuting KONG , Fengshi ZHANG , Zhiyi LU , Yanling LIU , Minglang YE , Zhengfang HU , Longsheng WANG , Bing HU , Haiying WANG . Research advance of the preparation of tributyl citrate catalyzed by supported heteropolyacid catalysts. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 441-452. doi: 10.11862/CJIC.20250303
10. [10]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . Thickness-Insensitive, Cyano-Modified Perylene Diimide Derivative as a Cathode Interlayer Material for High-Efficiency Organic Solar Cells. Acta Physico-Chimica Sinica, 2025, 41(3): 100027-0. doi: 10.3866/PKU.WHXB202406007
11. [11]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
12. [12]
  Jiarong Feng , Yejie Duan , Chu Chu , Dezhen Xie , Qiu'e Cao , Peng Liu . Preparation and Application of a Streptomycin Molecularly Imprinted Electrochemical Sensor: A Suggested Comprehensive Analytical Chemical Experiment. University Chemistry, 2024, 39(8): 295-305. doi: 10.3866/PKU.DXHX202401016
13. [13]
  Mengyun Wu , Yuxin Deng , Wenhui Wang , Dongdong Xu , Langui Xie , Peipei Sun . 电化学合成4-氯-2-三异丙基硅基喹啉. University Chemistry, 2026, 41(5): 222-229. doi: 10.12461/PKU.DXHX202511044
14. [14]
  Yue Zhang , Bao Li , Lixin Wu . GO-Assisted Supramolecular Framework Membrane for High-Performance Separation of Nanosized Oil-in-Water Emulsions. Acta Physico-Chimica Sinica, 2024, 40(5): 2305038-0. doi: 10.3866/PKU.WHXB202305038
15. [15]
  Yajin Li , Huimin Liu , Lan Ma , Jiaxiong Liu , Dehua He . Photothermal Synthesis of Glycerol Carbonate via Glycerol Carbonylation with CO₂ over Au/Co₃O₄-ZnO Catalyst. Acta Physico-Chimica Sinica, 2024, 40(9): 2308005-0. doi: 10.3866/PKU.WHXB202308005
16. [16]
  Xiaohang JIN , Qi LIU , Jianping LANG . Room‑temperature solid‑state synthesis, structure, and third‑order nonlinear optical properties of phosphine‑ligand‑protected silver thiolate clusters. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1505-1512. doi: 10.11862/CJIC.20250125
17. [17]
  Weikang Wang , Yadong Wu , Jianjun Zhang , Kai Meng , Jinhe Li , Lele Wang , Qinqin Liu . Green H₂O₂ synthesis via melamine-foam supported S-scheme Cd_0.5Zn_0.5In₂S₄/S-doped carbon nitride heterojunction: synergistic interfacial charge transfer and local photothermal effect. Acta Physico-Chimica Sinica, 2025, 41(8): 100093-0. doi: 10.1016/j.actphy.2025.100093
18. [18]
  Ruonan Li , Shijie Liang , Yunhua Xu , Cuifen Zhang , Zheng Tang , Baiqiao Liu , Weiwei Li . Chlorine-Substituted Double-Cable Conjugated Polymers with Near-Infrared Absorption for Low Energy Loss Single-Component Organic Solar Cells. Acta Physico-Chimica Sinica, 2024, 40(8): 2307037-0. doi: 10.3866/PKU.WHXB202307037
19. [19]
  Meng Aoyun , Li Zhenhua , Xiong Guoyuan , Li Zhen , Zhang Jinfeng . S-scheme heterojunction Al₆Si₂O₁₃/BiOBr with enhanced charge transfer effect for efficient and stable photocatalytic degradation of triazophos and dichlorvos pesticides. Acta Physico-Chimica Sinica, 2026, 42(5): 100186-. doi: 10.1016/j.actphy.2025.100186
20. [20]
  Jinghua Wang , Yanxin Yu , Yanbiao Ren , Yesheng Wang . Integration of Science and Education: Investigation of Tributyl Citrate Synthesis under the Promotion of Hydrate Molten Salts for Research and Innovation Training. University Chemistry, 2024, 39(11): 232-240. doi: 10.3866/PKU.DXHX202402057

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(575)
HTML views(52)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142