Citation: Li LIU, Lab Hai LI, Dong WANG. Regioselechve Reaction of α-(Alkoxydimethylsilyl)allyl Carbanions with Alkyl Halides and Aldehydes[J]. Chinese Chemical Letters, ;1996, 7(12): 1069-1072. shu

Regioselechve Reaction of α-(Alkoxydimethylsilyl)allyl Carbanions with Alkyl Halides and Aldehydes

Institute of Chtaltw Acadtala Sinica Beijing 100080

Received Date: 23 August 1996

Fund Project: We gratefully acknowledge the financial support of this research by the NSFC and the helpful suggestion by Professor T.H.Chan.

The reactions of α-(alkoxysilyl)allyl anions 4 with electrophiles were studied.α-Alkylation with alkyl halides was favoured,whereas γ-selection was achieved in the reaction with aldehydes.
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