Citation: Wen Hao SUN, Jing Mei YIN, Da Bin GAO, Guang Yun ZHOU, Ying Ping JIA, Xiang Sheng WANG. Photopromoted Methoxycarbonylation of Olefins Under Ambient Conditions in DMF[J]. Chinese Chemical Letters, ;2004, 15(10): 1245-1248. shu

Photopromoted Methoxycarbonylation of Olefins Under Ambient Conditions in DMF

1.
Department of Chemistry & Technology, Dalian University of Technology, Dalian 116012;
2.
Department of Chemistry and Chemical Engineering, Dalian University, Dalian 116622

Received Date: 25 August 2003

Fund Project: We are indebted to the National Natural Science Foundation of China (No.20242004, 20372012) and Foundations of Key Laboratory of Photochemistry, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences for the generous financial support.

Photopromoted methoxycarbonylation of olefins with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts in DMF. The isotope experiments show that DMF is decomposed under irradiation and is conveniently used as a carbon monoxide source for the reaction.
- Photopromoted methoxycarbonylation,
- carbon monoxide,
- DMF,
- isotope experiment
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