Citation: MENG Qing-Guo, ZHANG Ming-Hui, ZHANG Liang-Liang, WANG Rong-Ming, SUN Dao-Feng. A 3D Ba(Ⅱ) Inorganic-organic Hybrid Framework Based on 1,3,5-Benzenetricarboxylic Acid Ligand:Synthesis and Characterization[J]. Chinese Journal of Structural Chemistry, ;2014, 33(10): 1560-1565. shu

A 3D Ba(Ⅱ) Inorganic-organic Hybrid Framework Based on 1,3,5-Benzenetricarboxylic Acid Ligand:Synthesis and Characterization

1.
a Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China;
2.
b College of Science, China University of Petroleum(East China, Qingdao, Shandong 266580, China;
3.
c Chemistry & Chemical and Environmental Engineering College, Weifang University, Weifang, Shandong 261061, China

Received Date: 27 May 2014
Available Online: 12 September 2014
Fund Project: Supported by the Fundamental Research Funds for the Central Universities (13CX02006A, 14CX02158A) (13CX02006A, 14CX02158A)

A three-dimensional (3D) barium complex with 1,3,5-benzenetricarboxylic acid (H₃BTC), {[Ba_1.5(BTC)(H₂O)]·(H₂O)}_n (1), was synthesized in DMF/EtOH/H₂O mixed solution under solvothermal conditions, and characterized by single-crystal X-ray diffraction, elemental analyses, IR spectra, thermogravimetric analyses, and photoluminescence measurement. In complex 1, the 2D I²O⁰ type inorganic layer is constructed by {Ba₁O₁₀} and {Ba₂O₉} polyhedra. Moreover, the solid-state fluorescence measurement reveals a fluorescence emission band at 465 nm under 344 nm excitation, assigned to a charge-transfer transition.
- Ba(Ⅱ) complex,
- 1,3,5-benzenetricarboxylic acid,
- I2O0 type inorganic layer,
- fluorescence
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