Citation: PAN Cheng-Ling, ZHANG Lei, HU Jin-Song. Construction of a 2D Cd(Ⅱ) Network with Homohelical Chains Based on 1,3-Dipyridyl Benzene (Dpb) and 4,4'-Sulfonyldibenzoic Acid (H₂sdb)[J]. Chinese Journal of Structural Chemistry, ;2014, 33(10): 1533-1538. shu

Construction of a 2D Cd(Ⅱ) Network with Homohelical Chains Based on 1,3-Dipyridyl Benzene (Dpb) and 4,4'-Sulfonyldibenzoic Acid (H₂sdb)

1.
School of Chemical Engineering, School of Materials Science and Engineering, Laboratory of Multiscale Materials and Molecular Catalysis, Anhui University of Science and Technology, Huainan 232001, China

Corresponding author: HU Jin-Song,
Received Date: 24 March 2014
Available Online: 19 August 2014
Fund Project: This work was supported by the National Natural Science Foundation of China (21301005) (21301005)Natural Science Foundation of Anhui Province (1308085QB34, 1408085QB31) (1308085QB34, 1408085QB31)

A two-dimensional (2D) coordination polymer {[Cd₂(sdb)₂(dpb)₂]·3H₂O}_n (1) was prepared by solvothermal reaction of two types of V-shaped ligands:1,3-dipyridyl benzene (dpb) and deprotonated 4,4'-sulfonyldibenzoic acid (H₂sdb). It was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. Complex 1 crystallizes in the monoclinic system, space group Fdd2 with a=46.247(10), b=9.994(2), c=24.267(6) Å, V=11216(4) Å³, C₆₀H₄₆Cd₂N₄O₁₅S₂, M_r=1387.97, D_c=1.559 g/cm³, F(000)=5296.0, μ=0.902 mm^-1 and Z=8. Each[Cd(COO)]₂ cluster links four sdb^2- anions to form infinitely ABAB stacked 2D wave-like sheets, in which each sheet contains the same helical chains, and the helical directions of sheets A and B are reversed. Dpb links the rest coordinated sites of[(COO)Cd]₂ cluster to form a 2D network. In addition, the solid fluorescence of 1 and dpb is also studied.
- coordination polymer,
- V-shaped ligand,
- crystal structure,
- solid fluorescence
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