Citation: CHEN Li-Juan, YANG Ming-Xing, GUO Jing, ZHANG Qi-Kai, LIN Shen. Synthesis and Characterization of a Manganese(Ⅱ) Coordination Compound with Two-dimensional Layer Structure:{[Mn₂(IP)₂(1,4-bdc)₂]·H₂O}_n[J]. Chinese Journal of Structural Chemistry, ;2014, 33(10): 1499-1504. shu

Synthesis and Characterization of a Manganese(Ⅱ) Coordination Compound with Two-dimensional Layer Structure:{[Mn₂(IP)₂(1,4-bdc)₂]·H₂O}_n

CHEN Li-Juan ^a,b ,
YANG Ming-Xing ^a,b ,
GUO Jing ^a ,
ZHANG Qi-Kai ^b ,
LIN Shen ^a,b,,

1.
a College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou, Fujian 350007, China;
2.
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: LIN Shen,
Fund Project: This work was supported by the National Natural Science Foundation of of China (No. 21171037 & 21103021) (No. 21171037 & 21103021)the Natural Science Foundation of Fujian Province (No.2008I0013&No.2012J0142) (No.2008I0013&No.2012J0142)

A new complex {[Mn₂(IP)₂(1,4-bdc)₂]·H₂O}_n(1) (IP=1H-imidazo[4,5-f] [1,10]-phenanthroline, 1,4-H₂bdc=1,4-benzendicarboxylic acid), have been hydrothermally synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic, space group C_c with a=20.326(2), b=24.249(2), c=7.621(1) Å, β=108.546(6), V=3561.2(7) Å³, Z=4, D_c=1.672 g/cm³, μ=0.785 mm^-1, F(000)=1824, S=1.067, the final R=0.0299 and wR=0.0752. Compound 1 possesses a 2D structural motif, in which two crystallographically independent 1,4-bdc dianions adopt the alternative mode of mixed bis(bidentate) and monodentate-bidentate coordination modes to bridge neighboring Mn(Ⅱ) centers. And the 2D layers are linked up by hydrogen bonding and π…π stacking interactions to form a 3D network. The title compound has good thermal stability and exhibits photoluminescent emission maximum at 518 nm.
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