Citation: WANG Xiu-Yan, LIU Fu-Yi, KONG De-Yu. Synthesis, Crystal Structure and Luminescence of a New Zn(Ⅱ) Dimer:[Zn(bpdc)(L)]₂·4H₂O[J]. Chinese Journal of Structural Chemistry, ;2014, 33(10): 1495-1498. shu

Synthesis, Crystal Structure and Luminescence of a New Zn(Ⅱ) Dimer:[Zn(bpdc)(L)]₂·4H₂O

WANG Xiu-Yan ^a,b,, ,
LIU Fu-Yi ^a,b ,
KONG De-Yu ^a,b

1.
a Key Laboratory of Preparation and Applications of Environmental Friendly Materials, Ministry of Education, Siping 136000, China;
2.
b Department of Chemistry, Jilin Normal University, Siping 136000, China

Corresponding author: WANG Xiu-Yan,
Received Date: 27 February 2014
Available Online: 11 August 2014
Fund Project:

A new dimeric compound,[Zn(bpdc)(L)]₂·4H₂O (1, L=11-fluoro-dipyrido[3,2-a:2',3'-c]phenazine and bpdc=1,1'-biphenyl-2,2'-dicarboxylate), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic, space group C2/c with a=23.671(5), b=22.547(5), c=13.741(3) Å, β=123.47(3)°, V=6118(2) Å³, Z=4, C₆₆H₄₄Cl₂F₂N₈O₁₂Zn₂, M_r=1380.73, D_c=1.499 g/cm³, F(000)=2816, μ(MoKa)=0.949 mm^-1, R=0.0572 and wR=0.1620. In 1, Zn1 and the symmetry formed Zn1 ions are connected by four bridging bidentate carboxylate groups from two independent bpdc anions to yield a binuclear unit with the Zn…Zn separation by bpdc anions of 4.168 Å. Two L ligands are located on both sides of the dimer in chelating bidentate modes. The lateral L ligands from neighboring dimers are paired through strong π-π interactions to result in a fascinating 1D ladder-like supramolecular array. In addition, neighboring supramolecular ladders are packed each other to yield a 3D supramolecular architecture with a 1D channel.
- zinc complex,
- crystal structure,
- dimer,
- 1,1'-biphenyl-2,2'-dicarboxylate
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