Citation: HU Xiao-Jing, LI Long-Sheng, LIU Su-Yi, LIANG Zhi-Jie, NIU Jing-Yang. Synthesis and Characterization of a Bismuth Incorporating Heptamolybdate:(NH₄)₄[HMo₇O₂₄Bi(H₂O)₂C₅H₃N(CO₂)₂]·7H₂O[J]. Chinese Journal of Structural Chemistry, ;2014, 33(9): 1409-1414. shu

Synthesis and Characterization of a Bismuth Incorporating Heptamolybdate:(NH₄)₄[HMo₇O₂₄Bi(H₂O)₂C₅H₃N(CO₂)₂]·7H₂O

1.
Key Laboratory of Polyoxometalate Chemistry of Henan Province, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, China

Corresponding author: NIU Jing-Yang,
Received Date: 25 December 2013
Available Online: 14 April 2014
Fund Project:

A new one-dimensional molecule based on the linkage of[Mo₇O₂₄] clusters and[BiL] (L=pyridine-2,6-dicarboxylic acid) assembles under ambient conditions. The title compound was characterized by X-ray powder diffraction, IR and UV spectra, thermogravimetric analysis, and single-crystal X-ray diffraction. Crystal data:C₇H₃₈BiMo₇N₅O₃₇, M_r=1664.95, monoclinic, space group C2/c, a=24.312(2), b=21.4869(18), c=18.5423(16) Å, β=111.6490(10)°, V=9002.9(13) Å³, Z=8, μ=5.883 mm^-1, F(000)=6304, GOF=1.045, R=0.0365 and wR=0.1062.
- bismuth,
- heptamolybdate,
- crystal structure
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