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Citation: ZHANG Zhi-Jian, KUANG Dai-Zhi, ZHANG Fu-Xing, ZHU Xiao-Ming, YU Jiang-Xi, JIANG Wu-Jiu. Synthesis, Structure and Acaricidal Activity of Tricyclohexyltin Benzoate[J]. Chinese Journal of Structural Chemistry, ;2014, 33(9): 1287-1292. shu

Synthesis, Structure and Acaricidal Activity of Tricyclohexyltin Benzoate

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a Department of Life Sciences, Hengyang Normal University, Hengyang, Hunan 421008, China;
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b Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008, China

Received Date: 15 December 2013
Available Online: 11 July 2014
Fund Project: This research was supported by the Natural Science Foundation of Hunan Province (No.13JJ3112) (No.13JJ3112) Scientific & Technological Projects of Hunan Province (No. 2014FJ3060) (No. 2014FJ3060) the Open Fund Project of Key Laboratory in Hunan Universities (No.13K105) (No.13K105) Scientific Research Fund of Hunan Provincial Education Department of China (No.12C0537) (No.12C0537) the Construct Program of the Key Discipline in Hunan Province, Scientific & Technological Projects of Hengyang city (2011KG56, 2012KJ30) (2011KG56, 2012KJ30) Science Foundation of Hengyang Normal University (No.12C45) (No.12C45)the Youth Backbone Teacher Training Program of Hengyang Normal University (2012) (2012)

Tricyclohexyltin 4-amino-3-methyl-benzoate (1) and tricyclohexyltin 3,4-dimethoxybenzoate (2) were synthesized and their crystal structures were determined by X-ray diffraction. Compound 1 belongs to the monoclinic system, space group P2₁/c with a=14.0554(15), b=11.6947(13), c=16.2720(17) Å, Z=4, V=2565.7(5) Å³, Dc=1.341 g·cm^-3, μ(MoKα)=1.016 mm^-1, F(000)=1080, R=0.0833 and wR=0.2964. Compound 2 is of monoclinic system, space group C2/c with a=17.8712(6), b=8.4433(3), c=35.5783(13) Å, Z=8, V=5366.8(3) Å³, Dc=1.360 g·cm^-3, μ(MoKα)=0.980 mm^-1, F(000)=2288, R=0.0549, wR=0.1279. In compounds 1 and 2, the central Sn atom is coordinated in a tetradentate manner to assume a distorted tetrahedral configuration. Preliminary biological tests showed that these two compounds have strong acaricidal activity.
- organotin carboxylates,
- synthesis,
- crystal structure,
- acaricidal activity
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