Citation: Farzin Marandi. Syntheses, Crystal Structures, and Properties of a New Lead(Ⅱ) Complex Involving Holo- and Hemidirected Coordination Spheres with 3,5,6-Tris(2-pyridyl)-1,2,4-triazine Ligand[J]. Chinese Journal of Structural Chemistry, ;2014, 33(8): 1184-1190. shu

Syntheses, Crystal Structures, and Properties of a New Lead(Ⅱ) Complex Involving Holo- and Hemidirected Coordination Spheres with 3,5,6-Tris(2-pyridyl)-1,2,4-triazine Ligand

Farzin Marandi ^,

1.
Department of Chemistry, Payame Noor University, Tehran, Iran

Corresponding author: Farzin Marandi,
Received Date: 21 January 2014
Available Online: 23 May 2014

[Pb(TPT)(μ-I)₂PbI₂(μ-I)₂Pb(TPT)] 1 (TPT is the abbreviation of 3,5,6-tris(2-pyridyl)-1,2,4-triazine ligand) has been synthesized and characterized by elemental analysis, IR, ¹HNMR spectroscopy and studied by thermal and electrochemical properties as well as X-ray crystallography. The single-crystal X-ray data show two different kinds of Pb²⁺ ions in 1 with coordination numbers of six, Pb1=PbI₆, and five, Pb2=PbN₃I₂, with holodirected and hemidirected coordination spheres, respectively. The supramolecular features in 1 are negotiated through the weak but directional Pb…I, C-H…N and C-H…I interactions and aromatic π-π stacking interactions.
- lead(Ⅱ),
- crystal structure,
- holodirected,
- hemidirected,
- 1,2,4-triazine
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