Citation: WANG Ye, ZHAO Hong, LIU Zhong-Yi, YANG En-Cui, ZHAO Xiao-Jun. Synthesis, Structure and Magnetic Property of a New MOF with Triazolate and Azido Heterobridges[J]. Chinese Journal of Structural Chemistry, ;2014, 33(8): 1159-1163. shu

Synthesis, Structure and Magnetic Property of a New MOF with Triazolate and Azido Heterobridges

1.
College of Chemistry, Key Laboratory of Inorganic-organic Hybrid Functional Material Chemistry, Ministry of Education, Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300387, China

Received Date: 7 January 2014
Available Online: 25 March 2014
Fund Project: and Tianjin Educational Committee (2012ZD01) (TD52-5038)

A new magnetic MOF with cyclic triazolate and linear azido mediators, [Co₂(trz)₃(N₃)]_n 1 (trz^-=1,2,4-triazolate), was hydrothermally synthesized and structurally and magnetically characterized. 1 crystallizes in the rhombohedral P6₃/mmc space group with a=b=10.0716(17), c=7.5860(14) Å, V=666.4(2) Å³, D_c=1.814 g/cm³, M_r=364.09, Z=2, F(000)=360, μ=2.499 mm^-1, the final R=0.0676 and wR=0.1952 for 229 observed reflections with I>2σ(I). Complex 1 consists of linear {Co(trz)₃}_n chains passing through a C₆ rotation axis, which are interconnected with tetrahedral Co^Ⅱ ion by μ3-trz^- ligands into a hexagonal three-dimensional antiferromagnetic framework.
- triazolate,
- azide,
- magnetism,
- crystal structure
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